Data

NameSánchez Jiménez, Pedro Enrique
DepartmentQuímica Inorgánica
Knowledge areaQuímica Inorgánica
Professional categoryTalentia Senior (inv. Dist.)
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  Statistics

  • Items

    58

  • Visits

    3651

  • Downloads

    6908

  Publications

 

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Unveiling Mechanochemistry: kinematic-kinetic approach for the prediction of mechanically induced reactions

Gil González, Eva; Rodríguez-Laguna, María del Rocío; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Pérez Maqueda, Luis Allan (Elsevier, 2021-06-01)
Mechanochemistry has attracted a lot of attention over the last few decades with a rapid growth in the number of publications ...
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Kinetics and cyclability of limestone (CaCO3) in presence of steam during calcination in the CaL scheme for thermochemical energy storage

Arcenegui Troya, Juan Jesús; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Moreno, Virginia; Valverde Millán, José Manuel; Pérez Maqueda, Luis Allan (Elsevier, 2021-01-01)
In the present work, we explore the use of steam in the CaCO3 calcination step of a calcium looping process devised for ...
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Calcium-Looping Performance of Biomineralized CaCO3 for CO2 Capture and Thermochemical Energy Storage

Arcenegui Troya, Juan Jesús; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Valverde Millán, José Manuel; Chacartegui, Ricardo; Pérez Maqueda, Luis Allan (ACS Publications, 2020-07-01)
The commercial deployment of calcium-looping (CaL)-based technologies relies on the availability of nontoxic, widely ...
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Calcination under low CO2 pressure enhances the Calcium Looping performance of limestone for thermochemical energy storage

Sarrión Aceytuno, Beatriz; Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Amghar, Nabil; Chacartegui, Ricardo; Valverde Millán, José Manuel; Pérez Maqueda, Luis Allan (Elsevier, 2020-01-01)
The Calcium Looping performance of limestone for thermochemical energy storage has been investigated under novel favorable ...
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Role of particle size on the multicycle calcium looping activity of limestone for thermochemical energy storage

Durán Martín, Jonatan D.; Sánchez Jiménez, Pedro Enrique; Valverde Millán, José Manuel; Perejón Pazo, Antonio; Arcenegui Troya, Juan Jesús; García Triñanes, Pablo; Pérez Maqueda, Luis Allan (Elsevier, 2019-01-01)
The calcium looping process, based on the reversible reaction between CaCO3 and CaO, is recently attracting a great deal ...
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Calcium-Looping performance of mechanically modified Al2O3-CaO composites for energy storage and CO2 capture

Benítez Guerrero, Mónica; Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Pérez Maqueda, Luis Allan (Elsevier B.V., 2018-01-01)
This work reports the Calcium-Looping (CaL) multicycle performance under energy storage and CO2 capture conditions of ...
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Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power

Benítez Guerrero, Mónica; Valverde Millán, José Manuel; Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Elsevier BV, 2018-01-01)
An ever more environmentally conscious society demands the use of green, sustainable and high-efficiency renewable energy ...
PhD Thesis
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Estudio de cerámicas avanzadas (PDCs Polymer Derived Ceramics) obtenidas a partir de precursores poliméricos

Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; García Garrido, Cristina (2017-07-03)
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Calcium-Looping performance of steel and blast furnace slags for thermochemical energy storage in concentrated solar power plants

Valverde Millán, José Manuel; Miranda Pizarro, Juan; Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Elsevier BV, 2017-01-01)
The Calcium Looping (CaL) process, based on the carbonation/calcination of CaO, has been proposed as a feasible technology ...
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Multicycle activity of natural CaCO3 minerals for thermochemical energy storage in Concentrated Solar Power plants

Benítez Guerrero, Mónica; Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Pérez Maqueda, Luis Allan (Elsevier Ltd, 2017-01-01)
Thermochemical energy storage in Concentrated Solar Power plants by means of the Calcium-Looping process is a promising ...
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CO2 capture performance of Ca-Mg acetates at realistic Calcium Looping conditions

Miranda Pizarro, Juan; Perejón Pazo, Antonio; Valverde Millán, José Manuel; Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique (Elsevier BV, 2017-01-01)
The Calcium Looping (CaL) process, based on the cyclic carbonation/calcination of CaO, has emerged in the last years as a ...
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Structural and Chemical Characteristics of Sisal Fiber and Its Components: Effect of Washing and Grinding

Pérez Maqueda, Luis Allan; Artiaga, R; Benítez Guerrero, Mónica; Sánchez Jiménez, Pedro Enrique; Pascual Cosp, José (Taylor & Francis, 2017-01-01)
This work covers the study of microstructural changes of natural sisal fibers induced by different conditioning pre-treatments: ...
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Effect of Thermal Pretreatment and Nanosilica Addition on Limestone Performance at Calcium-Looping Conditions for Thermochemical Energy Storage of Concentrated Solar Power

Barea López, M.; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Valverde Millán, José Manuel (American Chemical Society, 2017-01-01)
The share of renewable energies is growing rapidly, partly in response to the urgent need for mitigating CO emissions from ...
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A Promising approach to the kinetics of crystallization processes: The sample controlled thermal analysis

Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel; Pérez Maqueda, Luis Allan (American Ceramic Society, 2017-01-01)
Constant Rate Thermal Analysis (CRTA) method implies controlling the temperature in such a way that the reaction rate is ...
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Flash sintering of highly insulating nanostructured phase-pure BiFeO3

Pérez Maqueda, Luis Allan; Gil González, Eva; Perejón Pazo, Antonio; Lebrun, J. M.; Sánchez Jiménez, Pedro Enrique; Raj, Rishi (American Ceramic Society, 2017-01-01)
We show that BiFeO, that is electrically homogeneous, is a good insulator, and has a low dielectric constant (the properties ...
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Effect of dolomite decomposition under CO2 on its multicycle CO2 capture behaviour under calcium looping conditions

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Parejón Pazo, Antonio; García Garrido, Cristina; Pérez Maqueda, Luis Allan; Calle Martos, Antonio de la (Royal Society of Chemistry, 2016-01-01)
One of the major drawbacks that hinder the industrial competitiveness of the calcium looping (CaL) process for CO capture ...
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Combined TGA-MS kinetic analysis of multistep processes. Thermal decomposition and ceramification of polysilazane and polysiloxane preceramic polymers.

García Garrido, Cristina; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Parejón Pazo, Antonio; Criado Luque, José Manuel (2016-01-01)
The polymer-to-ceramic transformation kinetics of two widely employed ceramic precursors; 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane ...
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Constant rate thermal analysis of a dehydrogenation reaction

Perejón Pazo, Antonio; Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel; Murafa, Nataliya; Subrt, Jan (Royal Society of Chemistry, 2016-01-01)
The Constant Rate Thermal Analysis (CRTA) procedure has been employed for the first time to study the kinetics of MgH2 ...
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Use of steel slag for CO2 capture under realistic calcium-looping conditions

Miranda Pizarro, Juan; Parejón Pazo, Antonio; Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Royal Society of Chemistry, 2016-01-01)
In this study, CaO derived from steel slag pretreated with diluted acetic acid has been tested as a dry sorbent for CO ...
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Magnesium hydride for energy storage applications: The kinetics of dehydrogenation under different working conditions

Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel; Pérez Maqueda, Luis Allan (Elsevier, 2016-01-01)
A new approach to the kinetics of magnesium hydride dehydrogenation is considered. A model able to predict the dehydrogenation ...
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New insights on the kinetic analysis of isothermal data: The independence of the activation energy from the assumed kinetic model

Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Pérez Maqueda, Luis Allan; Criado Luque, José Manuel (American Chemical Society, 2015-01-01)
Isothermal experiments are widely employed to study the kinetics of solid-state reactions or processes to extract essential ...
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Preparation of phase pure, dense fine grained ceramics by conventional and spark plasma sintering of La-substituted BiFeO3 nanoparticles

Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Poyato Galán, Rosalía; Masó, Nahum; West, Anthony R.; Criado Luque, José Manuel; Pérez Maqueda, Luis Allan (Elsevier, 2015-01-01)
High density ceramics of the system Bi1−xLaxFeO3, 0 ≤ x ≤ 0.15, have been prepared starting from nanoparticles obtained ...
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Applications of sample-controlled thermal analysis (SCTA) to kinetic analysis and synthesis of materials

Pérez Maqueda, Luis Allan; Criado Luque, José Manuel; Sánchez Jiménez, Pedro Enrique; Diánez Millán, María Jesús (Akadémiai Kiadó, 2015-01-01)
The advantages of the sample-controlled thermal analysis (SCTA) for both the kinetic analysis of solid-state reactions and ...
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Synthesis of a nanosilica supported CO2 sorbent in a fluidized bed reactor

Soria del Hoyo, Carlos; Valverde Millán, José Manuel; Ommen, J.R. van; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Sayagués de Vega, María Jesús (Elsevier, 2015-01-01)
CaO has been deposited on a nanosilica powder matrix by a procedure based on atomic layer deposition (ALD) in a fluidized ...
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Ca-looping for postcombustion CO2 capture: A comparative analysis on the performances of dolomite and limestone

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Pergamon Press, 2015-01-01)
The low cost and wide availability of natural limestone (CaCO3) is at the basis of the industrial competitiveness of the ...
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Comparison of thermal behavior of natural and hot-washed sisal fibers based on their main components: Cellulose, xylan and lignin. TG-FTIR analysis of volatile products

Benítez Guerrero, Mónica; López Beceiro, Jorge; Sánchez Jiménez, Pedro Enrique; Pascual Cosp, José (Elsevier, 2014-01-01)
This paper presents in a comprehensive way the thermal behavior of natural and hot-washed sisal fibers, based on the ...
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The effect of polymer matrices on the thermal hazard properties of RDX-based PBXs by using model-free and combined kinetic analysis

Yan, Qui-long; Zeman, S.; Sánchez Jiménez, Pedro Enrique; Zhao, Feng-Qi; Pérez Maqueda, Luis Allan; Malék, J. (Elsevier B.V., 2014-01-01)
In this paper, the decomposition reaction models and thermal hazard properties of 1,3,5-trinitro-1,3,5-triazinane (RDX) ...
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Characterization of thermally stable gamma alumina fibres biomimicking sisal

Benítez Guerrero, Mónica; Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; Pascual Cosp, José (Elsevier, 2014-01-01)
Mesoporous gamma alumina fibres of high surface area, stable up to 1000°C, were synthesized by bioreplica technique using ...
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Nanosilica supported CaO: A regenerable and mechanically hard CO2 sorbent at Ca-looping conditions

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Valverde Millán, José Manuel (Elsevier, 2014-01-01)
This work presents a CO2 sorbent that may be synthesized from low-cost and widely available materials following a simple ...
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Role of crystal structure on CO2 capture by limestone derived CaO subjected to carbonation/recarbonation/calcination cycles at Ca-looping conditions

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Sánchez Quintanilla, Miguel Angel (Elsevier, 2014-01-01)
Large scale pilot plants are currently demonstrating the feasibility of the Calcium-looping (CaL) technology built on the ...
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Multicyclic conversion of limestone at Ca-looping conditions: The role of solid-sate diffusion controlled carbonation

Sánchez Jiménez, Pedro Enrique; Valverde Millán, José Manuel; Pérez Maqueda, Luis Allan (2014-01-01)
Limestone derived CaO conversion when subjected to multiple carbonation/calcination cycles is a subject of interest currently ...
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Role of precalcination and regeneration conditions on postcombustion CO2 capture in the Ca-looping technology

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Elsevier, 2014-01-01)
The Ca-looping (CaL) technology is already recognized as a potentially viable method to capture CO2 from postcombustion ...
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High and stable Co2 capture capacity of natural limestone at Ca-looping conditions by heat pretreatment and recarbonation synergy

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Elsevier, 2014-01-01)
The Ca-looping (CaL) process, based on the multicyclic carbonation/ calcination of limestone derived CaO, has emerged ...
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Calcium-looping for post-combustion CO2 capture. On the adverse effect of sorbent regeneration under CO2

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Elsevier, 2014-01-01)
The multicyclic carbonation/calcination (c/c) of CaO solid particles at high temperature is at the basis of the recently ...
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Scission kinetic model for the prediction of polymer pyrolysis curves from chain structure

Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; Parejón Pazo, Antonio; García Garrido, Cristina; Benítez Guerrero, Mónica; Criado Luque, José Manuel (Elsevier, 2014-01-01)
There is a significant interest in correlating polymer structure with thermal degradation behavior. Thus, polymer pyrolysis ...
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Pyrolysis kinetics of ethylene-propylene (EPM) and ethylene-propylene-diene (EPDM)

Perejón Pazo, Antonio; Sánchez Jiménez, Pedro Enrique; Gil González, Eva; Pérez Maqueda, Luis Allan; Criado Luque, José Manuel (Elsevier, 2013-01-01)
The thermal degradation kinetics of several ethylene-propylene copolymers (EPM) and ethylene-propylene-diene terpolymers ...
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Comments on “Thermal decomposition of pyridoxine: an evolved gas analysision attachment mass spectrometry study”. About the application of modelfitting methods of kinetic analysis to single non-isothermal curves

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Criado Luque, José Manuel (John Wiley & Sons, 2013-01-01)
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Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Criado Luque, José Manuel (Elsevier, 2013-01-01)
The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators ...
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Clarifications regarding the use of model-fitting methods of kinetic analysis for determining the activation energy from a single non-isothermal curve

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Criado Luque, José Manuel (Chemistry Central, 2013-01-01)
Abstract Background This paper provides some clarifications regarding the use of model-fitting methods of kinetic analysis ...
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Limitations of model-fitting methods for kinetic analysis: Polystyrene thermal degradation

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Criado Luque, José Manuel (Elsevier, 2013-01-01)
In this paper, some clarifications regarding the use of model-fitting methods of kinetic analysis are provided in response ...
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Constant rate thermal analysis for enhancing the long-term CO2 capture of CaO at Ca-looping conditions

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Parejón Pazo, Antonio; Pérez Maqueda, Luis Allan (Elsevier, 2013-01-01)
Experimental results are reported on the (Ca-looping) multicyclic CO2 capture of CaO and nanosilica/CaO composites derived ...
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Electrical properties of stoichiometric BiFeO3 prepared by mechanosynthesis with either conventional or spark plasma sintering

Poyato Galán, Rosalía; Parejón Pazo, Antonio; Masó, Nahum; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel; Pérez Maqueda, Luis Allan (Wiley, 2013-01-01)
Phase-pure powders of stoichiometric BiFeO3 have been prepared by mechanosynthesis. Ceramics sintered by either conventional ...
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Kinetic studies in solid state reactions by sample-controlled methods and advanced analysis procedures

Pérez Maqueda, Luis Allan; Criado Luque, José Manuel; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio (Akadémiai Kiadó (Budapest), 2013-01-01)
A comparative study of both conventional rising temperature and sample-controlled methods, like constant rate thermal ...
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Direct mechanosynthesis of pure BiFeO3 perovskite nanoparticles: reaction mechanism

Perejón Pazo, Antonio; Murafa, Nataliya; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel; Diánez Millán, María Jesús; Pérez Maqueda, Luis Allan (Royal Society of Chemistry (Great Britain), 2013-01-01)
In this work, a mechanochemical procedure is proposed as a simple and fast method to synthesize the pure BiFeO3 perovskite ...
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CO2 multicyclic capture of pretreated/doped CaO in the Ca-looping process. Theory and experiments

Valverde Millán, José Manuel; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Pérez Maqueda, Luis Allan (Royal Society of Chemistry (Great Britain), 2013-01-01)
We study in this paper the conversion of CaO-based CO2 sorbents when subjected to repeated carbonation/calcination cycles ...
PhD Thesis
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Mecanosíntesis y caracterización de los materiales multiferroicos nanoestructurados Bi(1-x)RxFeO3 (R=La, Y)

Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio (2012-11-26)
En la presente tesis doctoral se aborda la preparación, por métodos mecanoquímicos, de materiales multiferroicos, entendiéndose ...
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Constant rate thermal analysis for thermal stability studies of polymers

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Criado Luque, José Manuel (Elsevier, 2011-01-01)
This paper explores the relationship between the shapes of temperature-time curves obtained from experimental data recorded ...
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Study of the dehydroxylation-rehydroxylation of pyrophyllite

Pérez Rodríguez, José Luis; Durán Benito, Adrián; Sánchez Jiménez, Pedro Enrique; Franquelo, María Luisa; Perejón Pazo, Antonio; Pascual-Cosp, José; Pérez Maqueda, Luis Allan (American Ceramic Society, 2010-01-01)
Pyrophyllite is a raw material of significant interest due to its large number of applications. Most of these applications ...
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Mechanochemical preparation of BaTiO3-Ni nanocomposites with high dielectric constant

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Diánez Millán, María Jesús; Perejón Pazo, Antonio; Criado Luque, José Manuel (Elsevier, 2010-01-01)
A mechanochemical procedure is proposed for an easy preparation of a BaTiO3-Ni composite in a single step. BaTiO3 and Ni ...
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Kinetic model for thermal dehydrochlorination of poly(vinyl chloride)

Sánchez Jiménez, Pedro Enrique; Perejón Pazo, Antonio; Criado Luque, José Manuel; Diánez Millán, María Jesús; Pérez Maqueda, Luis Allan (Elsevier, 2010-01-01)
In this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal ...
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Combined kinetic analysis of thermal degradation of polymeric materials under any thermal pathway

Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Perejón Pazo, Antonio; Criado Luque, José Manuel (Elsevier, 2009-01-01)
Combined kinetic analysis has been applied for the first time to the thermal degradation of polymeric materials. The ...
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Kissinger kinetic analysis of data obtained under different heating schedules

Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel; Pérez Maqueda, Luis Allan (Springer Netherlands, 2008-01-01)
The dynamic heating rate method developed by TA Instruments ( Hi-Res ™ ) is a kind of sample controlled ...
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Critical study of the isoconversional methods of kinetic analysis

Criado Luque, José Manuel; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan (Springer Verlag, 2008-01-01)
A critical study of the use of isoconversional methods for the kinetic analysis of non-isothermal data corresponding to ...
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Thermal characterization of Montmorillonite clays saturated with various cations

Balek, V.; Benes, M.; Subrt, Jan; Pérez Rodríguez, José Luis; Sánchez Jiménez, Pedro Enrique; Pérez Maqueda, Luis Allan; Pascual Cosp, José (Springer Verlag, 2008-01-01)
Emanation thermal analysis (ETA), thermogravimetry and high temperature XRD were used to characterize the thermal behavior ...
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Development of a universal sample controlled thermal analysis (SCTA) system for being used with any thermoanalytical instrument

Criado Luque, José Manuel; Pérez Maqueda, Luis Allan; Diánez Millán, María Jesús; Sánchez Jiménez, Pedro Enrique (Akadémiai Kiadó, 2007-01-01)
The SCTA method implies to control the te mperature in such a way that the reaction rate changes with the time ...
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Dependence of the preexponential factor on temperature

Criado Luque, José Manuel; Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique (Springer Verlag, 2005-01-01)
The dependence of the preexponential factor on the temperature has been examined and the errors involved in the activation ...
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Evaluation of the integral methods for the kinetic study of thermally stimulated processes in polymer science

Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel (Elsevier, 2005-01-01)
This paper reports on the accuracy of the integral methods used for the kinetic analysis of degradation and crystallization ...
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Kinetic analysis of solid-state reactions: Precision of the activation energy calculated by integral methods

Pérez Maqueda, Luis Allan; Sánchez Jiménez, Pedro Enrique; Criado Luque, José Manuel (Wiley, 2005-01-01)
The integral methods are extensively used for the kinetic analysis of solid-state reactions. As the Arrhenius integral ...