Artículo
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
Autor/es | Pérez Jiménez, Marina
Campos Manzano, Jesús López Serrano, Joaquín Carmona Guzmán, Ernesto |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2018 |
Fecha de depósito | 2019-08-16 |
Publicado en |
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Resumen | Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford hydrido-hydrocarbyl and bis(hydrocarbyl) derivatives of the Mo[quadruple bond, length as m-dash]Mo bond. ... Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford hydrido-hydrocarbyl and bis(hydrocarbyl) derivatives of the Mo[quadruple bond, length as m-dash]Mo bond. Reversible migratory insertion and β-hydrogen elimination, as well as reductive elimination and other reactions, have been uncovered. PhC[triple bond, length as m-dash]CH behaves instead as a Brönsted–Lowry acid towards the strongly basic Mo–H bonds of 1·THF. |
Identificador del proyecto | CTQ2016-75193-P
756575 |
Cita | Pérez Jiménez, M., Campos Manzano, J., López Serrano, J. y Carmona Guzmán, E. (2018). Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions. Chemical Communications, 54, 9186-9189. |
Ficheros | Tamaño | Formato | Ver | Descripción |
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10.1039_C8CC04945A.pdf | 964.9Kb | [PDF] | Ver/ | Versión postprint |