Article
A general algebraic model for molecular vibrational spectroscopy
Author/s | Frank, Alejandro
Lemus Casillas, Renato Bijker, R. Pérez Bernal, Francisco Arias Carrasco, José Miguel ![]() ![]() ![]() ![]() ![]() ![]() ![]() |
Department | Universidad de Sevilla. Departamento de Física Atómica, Molecular y Nuclear |
Publication Date | 1996 |
Deposit Date | 2019-04-15 |
Published in |
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Abstract | We introduce the anharmonic oscillator symmetry model to describe vibrational excitations in molecular systems exhibiting a high degree of symmetry. A systematic procedure is proposed to establish the relation between the ... We introduce the anharmonic oscillator symmetry model to describe vibrational excitations in molecular systems exhibiting a high degree of symmetry. A systematic procedure is proposed to establish the relation between the algebraic and configuration space formulations, leading to new interactions in the algebraic model. This approach incorporates the full power of group theoretical techniques and provides reliable spectroscopic predictions. We illustrate the method for the case of script D3h-triatomic molecules. |
Project ID. | CI1*-CT94-0072
![]() IN105194 ![]() 400340-5-3401E ![]() PB92-0663 ![]() |
Citation | Frank, A., Lemus Casillas, R., Bijker, R., Pérez Bernal, F. y Arias Carrasco, J.M. (1996). A general algebraic model for molecular vibrational spectroscopy. Annals of Physics, 252 (1), 211-238. |
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