Artículo
Boryl-assisted hydrogenolysis of a nickel–methyl bond
Autor/es | Curado Dianez, Natalia
Maya Díaz, Celia María López Serrano, Joaquín Rodríguez Iglesias, María Amor |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2014 |
Fecha de depósito | 2018-02-07 |
Publicado en |
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Resumen | A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the ... A stable Nickel(II) methyl complex containing a diphosphinoboryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a - B‒H Ni(0) species that further undergoes B‒H oxidative addition to form a Ni(II) hydride complex. |
Cita | Curado Dianez, N., Maya Díaz, C.M., López Serrano, J. y Rodríguez Iglesias, M.A. (2014). Boryl-assisted hydrogenolysis of a nickel–methyl bond. Chemical Communications, 50, 15718-15721. |
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Boryl-Assisted Hydrogenolysis.pdf | 1.437Mb | [PDF] | Ver/ | |