Article
A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles
Author/s | Martínez Prieto, Luis Miguel
Urbaneja, C. Palma Ramírez, María del Pilar Cámpora Pérez, Juan Philippot, Karine Chaudret, Bruno |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2015 |
Deposit Date | 2017-11-23 |
Published in |
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Abstract | The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the ... The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the metal surface takes place through the carbodiimide moiety. The resulting RuNPs led to decarbonylation of THF and showed size selectivity for styrene hydrogenation. |
Funding agencies | Junta de Andalucía European Union (UE) |
Project ID. | CTQ2012-30962
FQM6276 NANOSONWINGS 2009-246763 |
Citation | Martínez Prieto, L.M., Urbaneja, C., Palma, P., Cámpora, J., Philippot, K. y Chaudret, B. (2015). A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles. Chemical Communications, 51, 4647-4650. |
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