dc.creator | Gómez González, Margarita | es |
dc.creator | López Santos, Laura | es |
dc.creator | Paneque Sosa, Margarita | es |
dc.creator | Mereiter, Kurt | es |
dc.date.accessioned | 2017-04-10T12:30:44Z | |
dc.date.available | 2017-04-10T12:30:44Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Gómez González, M., López Santos, L., Paneque Sosa, M. y Mereiter, K. (2013). (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1- yl-κN 2)hydroborato]iridium(III). Acta Crystallographica Section E: Structure Reports Online, 69 (5), 234-235. | |
dc.identifier.issn | 1600-5368 | es |
dc.identifier.uri | http://hdl.handle.net/11441/57429 | |
dc.description.abstract | In the mononuclear title iridium(III) complex, [Ir(C4H8)-
(C15H22BN6)(C3H9P)], which is based on the [tris(3,5-
dimethylpyrazol-1-yl)hydroborato]iridium moiety, Ir[TpMe2],
the IrIII atom is coordinated by a chelating butane-1,4-diyl
fragment and a trimethylphosphane ligand in a modestly
distorted octahedral coordination environment formed by
three facial N, two C and one P atom. The iridium–butane-1,4-
diyl ring has an envelope conformation. This ring is disordered
because alternately the second or the third C atom of the
butane-1,4-diyl fragment function as an envelope flap atom
(the occupancy ratio is 1:1). In the crystal, molecules are
organized into densely packed columns extending along [101].
Coherence between the molecules is essentially based on van
der Waals interactions | es |
dc.description.sponsorship | FEDER CTQ2010–17476 | es |
dc.description.sponsorship | Consolider-Ingenio 2010 CSD2007–00006 | es |
dc.description.sponsorship | Junta de Andalucía FQM-119 P09-FQM-4832 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | International Union of Crystallography | es |
dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online, 69 (5), 234-235. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1- yl-κN 2)hydroborato]iridium(III) | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | CTQ2010–17476 | es |
dc.relation.projectID | CSD2007–00006 | es |
dc.relation.projectID | FQM-119 | es |
dc.relation.projectID | P09-FQM-4832 | es |
dc.relation.publisherversion | 10.1107/S1600536813008040 | es |
idus.format.extent | 13 p. | es |
dc.journaltitle | Acta Crystallographica Section E: Structure Reports Online | es |
dc.publication.volumen | 69 | es |
dc.publication.issue | 5 | es |
dc.publication.initialPage | 234 | es |
dc.publication.endPage | 235 | es |