Article
Solving the Hydration Structure of the Heaviest Actinide Aqua IonKnown: The Californium(III) Case
Author/s | Galbis Fuster, Elsa
Hernández Cobos, Jorge den Auwer, Christophe Le Naour, Ciaire Guillaumont, Dominique Simoni, Eric Rodríguez Pappalardo, Rafael Sánchez Marcos, Enrique |
Department | Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica Universidad de Sevilla. Departamento de Química Física |
Publication Date | 2010 |
Deposit Date | 2024-01-30 |
Published in |
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Abstract | Wish they all could be californium: X-ray absorption spectroscopy (black points) and Monte Carlo simulations (blue line) of Cf" in aqueous solutions have been combined to determine the ligand distance and coordination ... Wish they all could be californium: X-ray absorption spectroscopy (black points) and Monte Carlo simulations (blue line) of Cf" in aqueous solutions have been combined to determine the ligand distance and coordination number (CN) of the Cf" aqua ion (see picture), the heaviest cation measured and simulated to date. The results confirm that a contraction takes place in the actinide series as in the lanthanide series. |
Funding agencies | Junta de Andalucía |
Project ID. | P06-FQM-01484 |
Citation | Galbis Fuster, E., Hernández Cobos, J., den Auwer, C., Le Naour, C., Guillaumont, D., Simoni, E.,...,Sánchez Marcos, E. (2010). Solving the Hydration Structure of the Heaviest Actinide Aqua IonKnown: The Californium(III) Case. Angewandte Chemie - International Edition, 49 (22), 3811-3815. https://doi.org/10.1002/anie.200906129.. |
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