Artículo
A dicoordinate gold(i)–ethylene complex
Autor/es | Navarro, Miquel
Miranda Pizarro, Juan Moreno Díaz, Juan José Navarro Gilabert, Carlos Fernández, Israel Campos, Jesús |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2021 |
Fecha de depósito | 2023-06-09 |
Publicado en |
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Resumen | The use of the exceptionally bulky tris-2-(4,40
-di-tert-butylbiphenylyl)
phosphine ligand allows the isolation and complete characterization of
the first dicoordinate gold(I)–ethylene adduct, filling a missing fundamental ... The use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and complete characterization of the first dicoordinate gold(I)–ethylene adduct, filling a missing fundamental piece on the organometallic chemistry of gold. Besides, the bonding situation of this species has been investigated by means of state-of-the-art Density Functional Theory (DFT) calculations indicating that p-backdonation plays a minor role compared with tricoordinate analogues |
Agencias financiadoras | European Research Council (ERC) Ministerio de Ciencia e Innovación (MICIN). España |
Identificador del proyecto | 756575
PID2019-110856GA-I00 PID2019-106184GB-I00 RED2018-102387-T FJC2018-035514-I |
Cita | Navarro, M., Miranda Pizarro, J., Moreno Díaz, J.J., Navarro Gilabert, C., Fernández, I. y Campos, J. (2021). A dicoordinate gold(i)–ethylene complex. Chemical Communications, 57, 9280-9283. https://doi.org/10.1039/D1CC02769G. |
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