Article
Development of Power-to-X Catalytic Processes for CO2 Valorisation: From the Molecular Level to the Reactor Architecture
Author/s | Bobadilla Baladrón, Luis Francisco
Azancot Luque, Lola de las Aguas Luque Álvarez, Ligia Amelia Torres Sempere, Guillermo González Castaño, Míriam Pastor Pérez, Laura Ramírez Reina, Tomás Ivanova, Svetlana Odriozola Gordón, José Antonio |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2022 |
Deposit Date | 2023-05-25 |
Published in |
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Abstract | Nowadays, global climate change is likely the most compelling problem mankind is facing. In this scenario, decarbonisation of the chemical industry is one of the global challenges that the scientific community needs to ... Nowadays, global climate change is likely the most compelling problem mankind is facing. In this scenario, decarbonisation of the chemical industry is one of the global challenges that the scientific community needs to address in the immediate future. Catalysis and catalytic processes are called to play a decisive role in the transition to a more sustainable and low-carbon future. This critical review analyses the unique advantages of structured reactors (isothermicity, a wide range of residence times availability, complex geometries) with the multifunctional design of efficient catalysts to synthesise chemicals using CO2 and renewable H2 in a Power-to-X (PTX) strategy. Fine-chemistry synthetic methods and advanced in situ/operando techniques are essential to elucidate the changes of the catalysts during the studied reaction, thus gathering fundamental information about the active species and reaction mechanisms. Such information becomes crucial to refine the catalyst’s formulation and boost the reaction’s performance. On the other hand, reactors architecture allows flow pattern and temperature control, the management of strong thermal effects and the incorporation of specifically designed materials as catalytically active phases are expected to significantly contribute to the advance in the valorisation of CO2 in the form of high added-value products. From a general perspective, this paper aims to update the state of the art in Carbon Capture and Utilisation (CCU) and PTX concepts with emphasis on processes involving the transformation of CO2 into targeted fuels and platform chemicals, combining innovation from the point of view of both structured reactor design and multifunctional catalysts development. |
Funding agencies | Ministerio de Ciencia e Innovación (MICIN). España Junta de Andalucía |
Project ID. | RTI2018-096294-B-C33
PID2019-108502RJ-I00 IJC2019-040560-I US-1263288 P18-RT-3405 P20-0059 |
Citation | Bobadilla Baladrón, L.F., Azancot Luque, L.d.l.A., Luque Álvarez, L.A., Torres Sempere, G., González Castaño, M., Pastor Pérez, L.,...,Odriozola Gordón, J.A. (2022). Development of Power-to-X Catalytic Processes for CO2 Valorisation: From the Molecular Level to the Reactor Architecture. Chemistry, 4 (4), 1250-1280. https://doi.org/10.3390/chemistry4040083. |
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Development of Power-to-X.pdf | 4.445Mb | [PDF] | View/ | |