Article
Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions
Author/s | Ruiz López, Estela
Ribota Peláez, María Blasco Ruz, María Domínguez Leal, María Isabel Martínez Tejada, Leidy Marcela Ivanova, Svetlana |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2023 |
Deposit Date | 2023-04-20 |
Published in |
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Abstract | Formic acid has recently been revealed to be an excellent hydrogen carrier, and interest in the development of efficient and selective catalysts towards its dehydrogenation has grown. This reaction has been widely explored ... Formic acid has recently been revealed to be an excellent hydrogen carrier, and interest in the development of efficient and selective catalysts towards its dehydrogenation has grown. This reaction has been widely explored using homogeneous catalysts; however, from a practical and scalable point of view, heterogeneous catalysts are usually preferred in industry. In this work, formic acid dehydrogenation reactions in both liquid- and vapor-phase conditions have been investigated using heterogeneous catalysts based on mono- or bimetallic Pd/Ru. In all of the explored conditions, the catalysts showed good catalytic activity and selectivity towards the dehydrogenation reaction, avoiding the formation of undesired CO. |
Funding agencies | Ministerio de Ciencia e Innovación (MICIN). España Junta de Andalucía |
Project ID. | MCIN/AEI /10.13039/501100011033/
ENE2017-82451-C3-3-R PID2020-113809RB-C32 Grant P18-RT-3405 |
Citation | Ruiz López, E., Ribota Peláez, M., Blasco Ruz, M., Domínguez Leal, M.I., Martínez Tejada, M. y Ivanova, S. (2023). Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions. Materials, 16 (2), 472. https://doi.org/10.3390/ma16020472. |
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