dc.creator | González Castaño, Míriam | es |
dc.creator | Morales, Carlos | es |
dc.creator | Navarro de Miguel, Juan Carlos | es |
dc.creator | Boelte, Jens H. | es |
dc.creator | Klepel, Olaf | es |
dc.creator | Flege, Jan Ingo | es |
dc.creator | Arellano García, Harvey | es |
dc.date.accessioned | 2022-10-17T18:26:34Z | |
dc.date.available | 2022-10-17T18:26:34Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | González Castaño, M., Morales, C., Navarro de Miguel, J.C., Boelte, J.H., Klepel, O., Flege, J.I. y Arellano García, H. (2021). Are Ni/ and Ni5Fe1/biochar catalysts suitable for synthetic natural gas production? A comparison with γ-Al2O3 supported catalysts. Green Energy and Environment. https://doi.org/10.1016/j.gee.2021.05.007. | |
dc.identifier.issn | 2096-2797 | es |
dc.identifier.issn | 2468-0257 | es |
dc.identifier.uri | https://hdl.handle.net/11441/137977 | |
dc.description.abstract | Among challenges implicit in the transition to the post–fossil fuel energetic model, the finite amount of resources available for the technological implementation of CO2 revalorizing processes arises as a central issue. The development of fully renewable catalytic systems with easier metal recovery strategies would promote the viability and sustainability of synthetic natural gas production circular routes. Taking Ni and NiFe catalysts supported over γ-Al2O3 oxide as reference materials, this work evaluates the potentiality of Ni and NiFe supported biochar catalysts for CO2 methanation. The development of competitive biochar catalysts was found dependent on the creation of basic sites on the catalyst surface. Displaying lower Turn Over Frequencies than Ni/Al catalyst, the absence of basic sites achieved over Ni/C catalyst was related to the depleted catalyst performances. For NiFe catalysts, analogous Ni5Fe1 alloys were constituted over both alumina and biochar supports. The highest specific activity of the catalyst series, exhibited by the NiFe/C catalyst, was related to the development of surface basic sites along with weaker NiFe–C interactions, which resulted in increased Ni0:NiO surface populations under reaction conditions. In summary, the present work establishes biochar supports as a competitive material to consider within the future low-carbon energetic panorama. | es |
dc.description.sponsorship | Sasol Foundation gamma-Al2O3 | es |
dc.format | application/pdf | es |
dc.format.extent | 13 p. | es |
dc.language.iso | eng | es |
dc.publisher | KeAi Communications Co. | es |
dc.relation.ispartof | Green Energy and Environment. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Bimetallic catalysts | es |
dc.subject | Biochar catalysts | es |
dc.subject | Carbon catalysts | es |
dc.subject | CO2 methanation | es |
dc.subject | Ni catalysts | es |
dc.subject | NiFe alloy | es |
dc.subject | Synthetic natural gas | es |
dc.title | Are Ni/ and Ni5Fe1/biochar catalysts suitable for synthetic natural gas production? A comparison with γ-Al2O3 supported catalysts | es |
dc.type | info:eu-repo/semantics/article | es |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | gamma-Al2O3 | es |
dc.relation.publisherversion | https://doi.org/10.1016/j.gee.2021.05.007 | es |
dc.identifier.doi | 10.1016/j.gee.2021.05.007 | es |
dc.journaltitle | Green Energy and Environment | es |
dc.contributor.funder | Sasol Foundation | es |