Artículo
Epimerization of glucose over ionic liquid/phosphomolybdate hybrids: structure-activity relationship
Autor/es | Megías Sayago, Cristina
Álvarez González, Eleuterio Ivanova, Svetlana Odriozola Gordón, José Antonio |
Departamento | Universidad de Sevilla. Departamento de Química Inorgánica |
Fecha de publicación | 2018 |
Fecha de depósito | 2022-10-05 |
Publicado en |
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Resumen | The influence of the crystal structure and chemical nature of some ionic liquid/phosphomolybdate hybrids on their
catalytic activity in the epimerization of glucose is studied. A clear evidence for structure-activity ... The influence of the crystal structure and chemical nature of some ionic liquid/phosphomolybdate hybrids on their catalytic activity in the epimerization of glucose is studied. A clear evidence for structure-activity relationship is found. The inorganic part of the hybrid assures the active sites for the reaction; meanwhile the organic cation nature organizes the structure and controls the diffusion of the reactants. This study can be used as a first approach to predict the symmetry, long range order and active sites availability of the presented class of imidazolium based polyoxometalate hybrids. |
Cita | Megías Sayago, C., Álvarez González, E., Ivanova, S. y Odriozola Gordón, J.A. (2018). Epimerization of glucose over ionic liquid/phosphomolybdate hybrids: structure-activity relationship. Green Chemistry, 20, 1042-1049. https://doi.org/10.1039/c7gc03738d. |
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