Article
Thiodipropionate ZnII complexes: Synthesis, DFT studies, and X-ray structure of [{Zn(phen)(H2O)}2(μ-tdp) 2]·3H2O
Author/s | Grirrane, Abdessamad
Álvarez González, Eleuterio Pastor Navarro, Antonio Galindo del Pozo, Agustín |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2010 |
Deposit Date | 2022-06-27 |
Published in |
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Abstract | The zinc thiodipropionate complex [Zn(tdp)] (1) [tdp = S(CH 2CH2COO)22-] was obtained by reaction of aqueous zinc dichloride with a 1:1 mixture of Na2CO 3 and thiodipropionic acid. The bonding preferences of the tdp anion ... The zinc thiodipropionate complex [Zn(tdp)] (1) [tdp = S(CH 2CH2COO)22-] was obtained by reaction of aqueous zinc dichloride with a 1:1 mixture of Na2CO 3 and thiodipropionic acid. The bonding preferences of the tdp anion were studied by DFT methods. The reaction of 1 with o-phenanthroline (phen) gave the dinuclear compound [{Zn(phen)(H2O)}2(μ-tdp) 2]·3H2O (2), which was characterized by X-ray analysis. |
Citation | Grirrane, A., Álvarez González, E., Pastor Navarro, A. y Galindo del Pozo, A. (2010). Thiodipropionate ZnII complexes: Synthesis, DFT studies, and X-ray structure of [{Zn(phen)(H2O)}2(μ-tdp) 2]·3H2O. Zeitschrift fur Anorganische und Allgemeine Chemie, 636 (13-14), 2409-2412. |
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