dc.creator | Gandara Loe, Jesús | es |
dc.creator | Portillo Estévez, Esmeralda | es |
dc.creator | Odriozola Gordón, José Antonio | es |
dc.creator | Ramírez Reina, Tomás | es |
dc.creator | Pastor Pérez, Laura | es |
dc.date.accessioned | 2022-03-14T12:49:50Z | |
dc.date.available | 2022-03-14T12:49:50Z | |
dc.date.issued | 2021 | |
dc.identifier.citation | Gandara Loe, J., Portillo Estévez, E., Odriozola Gordon, J.A., Ramírez Reina, T. y Pastor Pérez, L. (2021). K-Promoted Ni-Based Catalysts for Gas-Phase CO2 Conversion: Catalysts Design and Process Modelling Validation. Frontiers in Chemistry, 9, 785571. | |
dc.identifier.issn | 2296-2646 | es |
dc.identifier.uri | https://hdl.handle.net/11441/130757 | |
dc.description.abstract | The exponential growth of greenhouse gas emissions and their associated climate change
problems have motivated the development of strategies to reduce CO2 levels via CO2
capture and conversion. Reverse water gas shift (RWGS) reaction has been targeted as a
promising pathway to convert CO2 into syngas which is the primary reactive in several
reactions to obtain high-value chemicals. Among the different catalysts reported for
RWGS, the nickel-based catalyst has been proposed as an alternative to the
expensive noble metal catalyst. However, Ni-based catalysts tend to be less active in
RWGS reaction conditions due to preference to CO2 methanation reaction and to the
sintering and coke formation. Due to this, the aim of this work is to study the effect of the
potassium (K) in Ni/CeO2 catalyst seeking the optimal catalyst for low-temperature RWGS
reaction. We synthesised Ni-based catalyst with different amounts of K:Ni ratio (0.5:10, 1:
10, and 2:10) and fully characterised using different physicochemical techniques where
was observed the modification on the surface characteristics as a function of the amount of
K. Furthermore, it was observed an improvement in the CO selectivity at a lower
temperature as a result of the K-Ni-support interactions but also a decrease on the
CO2 conversion. The 1K catalyst presented the best compromise between CO2
conversion, suppression of CO2 methanation and enhancing CO selectivity. Finally, the
experimental results were contrasted with the trends obtained from the thermodynamics
process modelling observing that the result follows in good agreement with the modelling
trends giving evidence of the promising behaviour of the designed catalysts in CO2 highscale units. | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación PID2019-108502RJ-I00 IJC2019-040560-I | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación RYC2018-024387-I | es |
dc.format | application/pdf | es |
dc.format.extent | 13 p. | es |
dc.language.iso | eng | es |
dc.publisher | Frontiers Media | es |
dc.relation.ispartof | Frontiers in Chemistry, 9, 785571. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | CO2 valorisation | es |
dc.subject | Alkali promoters | es |
dc.subject | Ni-based catalysts | es |
dc.subject | RWGS | es |
dc.subject | Low temperature | es |
dc.subject | Potassium | es |
dc.title | K-Promoted Ni-Based Catalysts for Gas-Phase CO2 Conversion: Catalysts Design and Process Modelling Validation | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | PID2019-108502RJ-I00 | es |
dc.relation.projectID | IJC2019-040560-I | es |
dc.relation.projectID | RYC2018-024387-I | es |
dc.relation.publisherversion | https://doi.org/10.3389/fchem.2021.785571 | es |
dc.identifier.doi | 10.3389/fchem.2021.785571 | es |
dc.journaltitle | Frontiers in Chemistry | es |
dc.publication.volumen | 9 | es |
dc.publication.initialPage | 785571 | es |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | es |