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Artículo
Zero-valent ML2complexes of Group 10 Metals Supported by Terphenyl Phosphanes
(Royal Society of Chemistry, 2021)
Bulky terphenyl phosphane ligands PMe2Ar′ (Ar′ = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in ...
Artículo
Palladium-mediated Intramolecular Dearomatization of Ligated Dialkylterphenyl Phosphines
(Royal Society of Chemistry, 2019)
Aryl-Pd(ii) chlorides stabilized by dialkylterphenyl phosphine ligands undergo a thermal isomerization process, leading to the formation of allyl-Pd(ii)-chloride species. The transformation involves the intramolecular ...
Artículo
Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
(American Chemical Society, 2014)
Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully characterized. Related species have been postulated as key intermediates in carbon–heteroatom coupling ...