Buscar
Mostrando ítems 1-4 de 4
Artículo
Structural diversity and magnetic properties of copper(ii) quinaldinate compounds with amino alcohols
(Royal Society of Chemistry, 2022)
The reactions between [Cu(quin)2(H2O)] (quin− = the anionic form of quinoline-2-carboxylic acid) and a series of aliphatic amino alcohols have yielded structurally very diverse copper(II) complexes, labelled a–g. Single-crystal ...
Artículo
Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
(Elsevier, 2019)
The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ (R = alkyl; Ar’ = C6H3-2,6-Ar2), have been evaluated by various methods. Their σ-donating capacity ...
Artículo
Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
(American Chemical Society, 2014)
Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully characterized. Related species have been postulated as key intermediates in carbon–heteroatom coupling ...
Artículo
Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
(Wiley-Blackwell, 2020)
The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by treatment of the ligand precursor 4 with Ag2O followed by reaction with [IrCl(COE)2]2. The chlorohydride ...