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Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
(John Wiley & Sons, 2016)
The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes to form the corresponding σ-SiH complexes. According to DFT calculations, the most stable coordination ...