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Tesis Doctoral
DYKAT and desymmetrization strategies for the synthesis of axially chiral heterobiaryls
(2020-01-31)
The main objective of this PhD thesis is the development of new methodologies for the synthesis of axially chiral heterobiaryls through asymmetric functionalization of this type of systems. In this regard, the approaches ...
Artículo
Room Temperature Ionic Liquids in Asymmetric Hetero-Ene Type Reactions: Improving Organocatalyst Performance at Lower Temperatures
(MDPI, 2021-01)
Abstract: Room temperature ionic liquids (RTILs) have been widely used as (co)solvents in several catalytic processes modifying, in most of the cases, the catalyst activity and/or the selectivity for the studied reactions. ...
Artículo
Pd-Catalyzed Dynamic Kinetic Asymmetric Cross-Coupling of Heterobiaryl Bromides with N-Tosylhydrazones
(American Chemical Society, 2022)
A dynamic kinetic asymmetric Pd-catalyzed cross-coupling reaction of heterobiaryl bromides with ketone N-tosylhydrazones for the synthesis of heterobiaryl styrenes is described. The combination of Pd(dba)2 as a precatalyst ...
Tesis Doctoral
Hydrazones as C-Nucleophiles in Asymmetric Organocatalysis
(2021-06-25)
In this PhD Thesis, novel catalytic processes and methodologies for the asymmetric functionalization of prochiral substrates (neutral or ionic) employing hydrazones as versatile umpolung reagents have been developed. In ...
Tesis Doctoral
Desarrollo de reacciones de inserción y adición catalizadas por complejos de oro (I)
(2022-06-13)
La presente Tesis Doctoral tiene como objetivo principal el desarrollo de nuevas aplicaciones de complejos organometálicos de oro (I) en catálisis homogénea. En concreto, se ha estudiado la eficiencia de distintos catalizadores ...
Tesis Doctoral
Atroposelective Synthesis of (Hetero)biaryls: Dynamic Kinetic and Thermodynamic Control of the Axial Chirality
(2023-04-14)
The main goal of this PhD thesis has been the development of catalytic asymmetric methodologies for the synthesis of axially chiral (hetero)biaryls through dynamization strategies. These methodologies comprise the use of ...