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Listar por autor "Moreno Díaz, Juan José"
Mostrando ítems 1-20 de 20
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Artículo
A dicoordinate gold(i)–ethylene complex
Navarro, Miquel; Miranda Pizarro, Juan; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Fernández, Israel; Campos, Jesús (Royal Society of Chemistry, 2021)The use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and ...
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Artículo
Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
Moreno Díaz, Juan José; Fernández Espada-Pastor, María; Campos Manzano, Jesús; López Serrano, Joaquín; Macgregor, Stuart A.; Carmona Guzmán, Ernesto (American Chemical Society, 2019)C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ...
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Artículo
Electrocatalytic CO2 Reduction with a Binuclear Bis-Terpyridine Pyrazole-Bridged Cobalt Complex
Bohn, Antoine; Moreno Díaz, Juan José; Thuery, Pierre; Robert, Marc; Rivada Wheelaghan, Orestes (Wiley-VCH GmbH, 2023)A pyrazole-based ligand substituted with terpyridine groups at the 3 and 5 positions has been synthesized to form the ...
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Artículo
Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
Hidalgo, Nereida; Moreno Díaz, Juan José; García Rubio, Inés; Campos, Jesús (Wiley, 2022)The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed-shell states. The reactivity ...
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Artículo
Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
Marín Gómez, Mario; Moreno Díaz, Juan José; Alcaide, María M.; Álvarez González, Eleuterio; López Serrano, Joaquín; Campos Manzano, Jesús; Nicasio Jaramillo, María del Carmen; Carmona Guzmán, Ernesto (Elsevier, 2019)The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ...
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Artículo
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
Hidalgo, Nereida; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Maya Díaz, Celia María; López Serrano, Joaquín; Campos Manzano, Jesús (Wiley-Blackwell, 2020)A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) ...
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Artículo
Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides
Jori, Nadir; Moreno Díaz, Juan José; Shivaraam, R. A.Keerthi; Rajeshkumar, Thayalan; Scopelliti, Rosario; Maron, Laurent; Mazzanti, Marinella (Royal Society of Chemistry, 2024-04-02)End-on binding of dinitrogen to low valent metal centres is common in transition metal chemistry but remains extremely ...
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Artículo
Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis
G. Alférez, Macarena; Moreno Díaz, Juan José; Gaona, Miguel A.; Maya Díaz, Celia María; Campos, Jesús (American Chemical Society, 2023)The incorporation of boron functionalities into transition-metal catalysts has become a promising strategy to improve ...
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Artículo
Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines
Moreno Díaz, Juan José; Fernández Espada, María; Krüger, Eric; López Serrano, Joaquín; Campos, Jesús; Carmona Guzmán, Ernesto (Wiley, 2018)We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by ...
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Mechanism of Dihydrogen Splitting by An Apparent Bimetallic Frustrated Lewis Pair based on Ir(III)/Pt(0)
Moreno Díaz, Juan José; Pita Milleiro, Alejandra; Luque Gómez, Ana; Espada, María F.; López Serrano, Joaquín; Campos, Jesús (Wiley-Blackwell, 2023)The incorporation of transition metals into frustrated Lewis pairs (FLPs) offers multiple opportunities for bond activation ...
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Artículo
Polarized Au(i)/Rh(i) Bimetallic Pairs Cooperatively Trigger Ligand Non-innocence and Bond Activation
Alférez, Macarena G.; Moreno Díaz, Juan José; Maya Díaz, Celia María; Campos, Jesús (Royal Society of Chemistry, 2023)The combination of molecular metallic fragments of contrasting Lewis character offers many possibilities for cooperative ...
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Artículo
Reactivity of a gold(i)/platinum(0) frustrated Lewis pair with germanium and tin dihalides
Hidalgo, Nereida; Bajo Velázquez, Sonia; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Mercado, Brandon Q.; Campos Manzano, Jesús (Royal Society of Chemistry, 2019)The reactivity of germanium and tin dichlorides with a transition metal-only frustrated Lewis pair based on Au(i) and Pt(0) ...
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Artículo
Reductive C–C Coupling from Molecular Au(I) Hydrocarbyl Complexes: A Mechanistic Study
Miranda Pizarro, Juan; Luo, Zhongwen; Moreno Díaz, Juan José; Dickie, Diane A.; Campos Manzano, Jesús; Brent Gunnoe, T. (American Chemical Society, 2021)Organometallic gold complexes are used in a range of catalytic reactions, and they often serve as catalyst precursors that ...
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Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach
Alférez, Macarena G.; Moreno Díaz, Juan José; Hidalgo Reinoso, Nereida; Campos, Jesús (Wiley, 2020)The use of cyclopentadienyl ligands in organome-tallic chemistry and catalysis is ubiquitous, mostly due to theirrobust ...
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Artículo
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
Navarro, Miquel; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Campos, Jesús (Royal Society of Chemistry, 2022-09-06)There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for ...
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Artículo
Synthesis, properties, and some rhodium, iridium, and platinum complexes of a series of bulky m-terphenylphosphine ligands
Ortega Moreno, Laura; Fernández Espada, María; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Campos Manzano, Jesús; Conejero Iglesias, Salvador; López Serrano, Joaquín; Maya Díaz, Celia María; Peloso, Riccardo; Carmona Guzmán, Ernesto (Elsevier, 2016)A series of sterically demanding aryl phosphine ligands (L) bearing terphenyl substituents, PR2Ar′ (R = hydrocarbyl, Ar′ ...
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Tesis Doctoral
Synthesis, reactivity and computational studies of ir complexes bearing terphenyl phosphine ligands.
Moreno Díaz, Juan José (2019-02-08) -
Artículo
Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines
Marín Gómez, Mario; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Nicasio Jaramillo, María del Carmen; Carmona Guzmán, Ernesto (Wiley, 2019)The experimental and computational characterization of a series of dialkylterphenyl phosphines, PR2Ar′ is described. The ...
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Artículo
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
Hidalgo, Nereida; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Maya Díaz, Celia María; López Serrano, Joaquín; Campos, Jesús (American Chemical Society, 2020)Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. ...
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Artículo
Unveiling the Latent Reactivity of Cp* Ligands (C5Me5-) toward Carbon Nucleophiles on an Iridium Complex
Pita Milleiro, Alejandra; Alférez, Macarena G.; Moreno Díaz, Juan José; Espada, María F.; Maya Díaz, Celia María; Campos, Jesús (American Chemical Society, 2023)The divergent reactivity of the cationic iridium complex [(η5-C5Me5)IrCl(PMe2ArDipp2)]+ (ArDipp2 = C6H3-2,6-(C6H3-2,6-iPr2)2) ...