idUS - Author profile: Ríos Moreno, Pablo

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Name	Ríos Moreno, Pablo
Department	Química Inorgánica
Knowledge area	Química Inorgánica
Professional category	Profesor Contratado Doctor
E-mail	Request

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15
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1472
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2794

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Publications
Article Cleavage of Carbon Dioxide C=O Bond Promoted by Nickel-Boron Cooperativity in a PBP-Ni Complex Álvarez Rodríguez, Lucía; Ríos Moreno, Pablo; Laglera Gandara, Carlos J.; Jurado, Andrea; Fernández de Córdova, Francisco José; Gunnoe, T. Brent; Rodríguez, Amor (Wiley-Blackwell, 2023) The synthesis and characterization of (tBuPBP)Ni(OAc) (5) by insertion of carbon dioxide into the Ni−C bond of (tBuPBP)NiMe ...
Article Tetracopper σ-Bound μ-Acetylide and -Diyne Units Stabilized by a Naphthyridine-based Dinucleating Ligand Ríos Moreno, Pablo; See, Matthew S.; Handford, Rex C.; Cooper, Jason K.; Don Tilley, T. (Wiley-Blackwell, 2023) Reactions of a dicopper(I) tert-butoxide complex with alkynes possessing boryl or silyl capping groups resulted in formation ...
Article Bonding Situation of σ-E−H Complexes in Transition Metal and Main Group Compounds Ríos Moreno, Pablo; Conejero, Salvador; Fernández, Israel (Wiley-Blackwell, 2022) The ambiguous bonding situation of σ-E−H (E=Si, B) complexes in transition metal compounds has been rationalized by means ...
Article Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different Ríos Moreno, Pablo; Rodríguez, Amor; Conejero, Salvador (Royal Society of Chemistry, 2022) In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
Article Reversible carbon-boron bond formation at platinum centers through σ-BH complexes Ríos Moreno, Pablo; Martín de la Calle, Rocío; Vidossich, Pietro; Fernández de Córdova Martín, Francisco José; Lledós, Agustí; Conejero, Salvador (Royal Society of Chemistry, 2021) A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, ...
Article Ligand Effects in Carbon−Boron Coupling Processes Mediated by σ-BH Platinum Complexes Ríos Moreno, Pablo; Fernández de Córdova, Francisco José; Borge, Javier; Curado, Natalia; Lledós, Agustí; Conejero, Salvador (Wiley, 2021) The reaction of tri-coordinated boranes (derived from dioxaborolanes and diazaborolanes) with cyclometalated low-electron ...
Article Hydrosilylation of Carbonyl Compounds Catalyzed by a Nickel Complex Bearing a PBP Ligand Fernández, José Antonio; García, Juan Manuel; Ríos Moreno, Pablo; Rodríguez, Amor (Wiley, 2021) The efficient catalytic hydrosilylation of ketones and aldehydes has been investigated using a nickel pincer hydride complex ...
Article Ambiphilic boryl groups in a neutral Ni(ii) complex: a new activation mode of H2 Ríos Moreno, Pablo; Borge, Javier; Fernández de Córdova Martín, Francisco José; Sciortino, Giuseppe; Lledós, Agustí; Rodríguez, Amor (Royal Society of Chemistry, 2021) The concept of metal–ligand cooperation opens new avenues for the design of catalytic systems that may offer alternative ...
Article Enhancing the catalytic properties of well-defined electrophilic platinum complexes Ríos Moreno, Pablo; Rodríguez, Amor; Conejero, Salvador (Royal Society of Chemistry, 2020) Platinum complexes have been often considered as the least reactive of the group 10 triad metals. Slow kinetics are behind ...
PhD Thesis Compuestos organometálicos en reacciones de acoplamiento deshidrogenante, transformación de dióxido de carbono y otros procesos catalíticos. Ríos Moreno, Pablo; Conejero Iglesias, Salvador; Rodríguez Iglesias, María Amor (2019) El objetivo de esta Tesis Doctoral consiste en el empleo de ligandos con diferentes propiedades estereoelectrónicas y su ...
Article σ-Silane Platinum(II) Complexes as Intermediates in C−Si Bond-Coupling Processes Ríos Moreno, Pablo; Fouilloux, Hugo; Díez, Josefina; Vidossich, Pietro; Lledós, Agustí; Conejero Iglesias, Salvador (Wiley, 2019) Platinum complexes [Pt(NHC’)(NHC)][BArF] (NHC’ denotes the cyclometallated N-heterocyclic carbene ligand, NHC) react with ...
Article Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings Ríos Moreno, Pablo; Roselló Merino, Marta; Rivada Wheelaghan, Orestes; Borge, Javier; López Serrano, Joaquín; Conejero Iglesias, Salvador (Royal Society of Chemistry, 2018) Platinum(II) complex [Pt(It Bu0 )(It Bu)][BArF 4] (1a) is a highly active and selective catalyst in the dehydrocoupling ...
Article Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation Ríos Moreno, Pablo; Díez, Josefina; López Serrano, Joaquín; Rodríguez, Amor; Conejero, Salvador (John Wiley & Sons, 2016) The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ...
Article Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex Ríos Moreno, Pablo; Rodríguez, Amor; López Serrano, Joaquín (American Chemical Society, 2016) This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
Article Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex Ríos Moreno, Pablo; Curado, Natalia; López Serrano, Joaquín; Rodríguez, Amor (American Chemical Society, 2016) Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ...