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Nature of the "Z"-phase in layered Na-ion battery cathodes


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Opened Access Nature of the "Z"-phase in layered Na-ion battery cathodes

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Author: Somerville, James W.
Sobkowiak, Adam
Tapia-Ruiz, Nuria
Billaud, Juliette
Lozano Suárez, Juan Gabriel
House, Robert A.
Gallington, Leighanne C.
Ericsson, Tore
Häggström, Lennart
Roberts, Matthew R.
Maitra, Urmimala
Bruce, Peter G.
Department: Universidad de Sevilla. Departamento de Ingeniería y Ciencia de los Materiales y del Transporte
Date: 2019-05-17
Published in: Energy and Environmental Science, 12 (7), 2223-2232.
Document type: Article
Abstract: Layered sodium transition metal oxides with the P2 structure, e.g. Na2/3[Ni1/3Mn2/3]O2, are regarded as candidates for Na-ion battery cathodes. On charging, extraction of Na destabilizes the P2 phase (ABBA oxide ion stacking) in which Na+ is in trig...
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Cite: Somerville, J.W., Sobkowiak, A., Tapia-Ruiz, N., Billaud, J., Lozano Suárez, J.G., House, R.A.,...,Bruce, P.G. (2019). Nature of the Z-phase in layered Na-ion battery cathodes. Energy and Environmental Science, 12 (7), 2223-2232.
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DOI: 10.1039/c8ee02991a

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