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Synthesis and reactivity of half-sandwich (η 5 -C 5 Me 5 )Ir(iii) complexes of a cyclometallated aryl phosphine ligand

 

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Opened Access Synthesis and reactivity of half-sandwich (η 5 -C 5 Me 5 )Ir(iii) complexes of a cyclometallated aryl phosphine ligand
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Author: Campos Manzano, Jesús
Álvarez González, Eleuterio
Carmona Guzmán, Ernesto
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2011
Published in: New Journal of Chemistry, 35 (10), 2122-2129.
Document type: Article
Abstract: Reaction of the Ir(iii) dimer [(η 5 -C 5 Me 5 )IrCl 2 ] 2 with PMeXyl 2 (Xyl = 2,6-C 6 H 3 Me 2 ), in the presence of the poorly coordinating base 2,2,6,6-tetramethyl piperidine, gives a chloride complex 1-Cl, resulting from hydrogen chloride elimin...
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Cite: Campos Manzano, J., Álvarez González, E. y Carmona Guzmán, E. (2011). Synthesis and reactivity of half-sandwich (η 5 -C 5 Me 5 )Ir(iii) complexes of a cyclometallated aryl phosphine ligand. New Journal of Chemistry, 35 (10), 2122-2129.
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URI: https://hdl.handle.net/11441/88012

DOI: 10.1039/c1nj20244h

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