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Large-scale preparation and labelling reactions of deuterated silanes

 

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dc.creator Campos Manzano, Jesús es
dc.creator Rubio Moreno, Miguel es
dc.creator Esqueda Oliva, Ana Cristina es
dc.creator Carmona Guzmán, Ernesto es
dc.date.accessioned 2018-10-10T14:49:39Z
dc.date.available 2018-10-10T14:49:39Z
dc.date.issued 2012
dc.identifier.citation Campos Manzano, J., Rubio Moreno, M., Esqueda Oliva, A.C. y Carmona Guzmán, E. (2012). Large-scale preparation and labelling reactions of deuterated silanes. Journal of Labelled Compounds and Radiopharmaceuticals, 55, 29-38.
dc.identifier.issn 0362-4803 (impreso) es
dc.identifier.issn 1099-1344 (electrónico) es
dc.identifier.uri https://hdl.handle.net/11441/79316
dc.description.abstract A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation in a 3–4 g scale, utilizing D2 (0.5 bar) as the hydrogen isotope source and low catalyst loadings (0.01 mol%). The catalyst precursor is the rhodium (III) complex 1, which contains a (η5‐C5Me5)Rh cation stabilized by coordination to a cyclometallated phoshine PMeXyl2 (Xyl = 2,6‐C6H3Me2). The same complex is also an active catalyst for the hydrosilylation of the CO and C≡N bonds of various ketones, aldehydes and α,β‐unsaturated nitriles. Hence, combination of these two properties permits development of a simple and proficient one‐flask, two‐step procedure for the deuterosilylation of these substrates. es
dc.description.sponsorship Ministerio de Ciencia y Tecnología CTQ2010‐17476, Consolider‐Ingenio 2010 CSD2007‐00006 es
dc.description.sponsorship Junta de Andalucía FQM‐119, P09‐FQM‐4832 es
dc.description.sponsorship Ministerio de Educación AP20080256 es
dc.description.sponsorship CONACYT (Mexico) 22934 es
dc.format application/pdf es
dc.language.iso eng es
dc.publisher John Wiley & Sons es
dc.relation.ispartof Journal of Labelled Compounds and Radiopharmaceuticals, 55, 29-38.
dc.rights Attribution-NonCommercial-NoDerivatives 4.0 Internacional *
dc.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/ *
dc.subject Deuterium es
dc.subject Deuterium exchange es
dc.subject Rhodium es
dc.subject Silanes es
dc.subject Deuterosilylation es
dc.subject Catalysis es
dc.title Large-scale preparation and labelling reactions of deuterated silanes es
dc.type info:eu-repo/semantics/article es
dc.type.version info:eu-repo/semantics/submittedVersion es
dc.rights.accessrights info:eu-repo/semantics/openAccess es
dc.contributor.affiliation Universidad de Sevilla. Departamento de Química Inorgánica es
dc.relation.projectID CTQ2010‐17476 es
dc.relation.projectID Consolider‐Ingenio 2010 CSD2007‐00006 es
dc.relation.projectID FQM‐119 es
dc.relation.projectID P09‐FQM‐4832 es
dc.relation.projectID AP20080256 es
dc.relation.projectID 22934 es
dc.relation.publisherversion https://doi.org/10.1002/jlcr.1950 es
dc.identifier.doi 10.1002/jlcr.1950 es
idus.format.extent 25 es
dc.journaltitle Journal of Labelled Compounds and Radiopharmaceuticals es
dc.publication.volumen 55 es
dc.publication.initialPage 29 es
dc.publication.endPage 38 es
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