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Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex

 

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Opened Access Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
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Author: Ríos Moreno, Pablo
Curado, Natalia
López Serrano, Joaquín
Rodríguez Iglesias, María Amor
Date: 2016
Published in: Chemical Communications, 52, 2114-2117.
Document type: Article
Abstract: The selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have been developed for this reaction. Herein, we report an efficient catalyst that consists of a bis(phosphino)boryl nickel hydride complex in combination with B(C6F5)3, for the highly selective hydrosilation of CO2 to bis(silyl)acetal derivatives.
Cite: Ríos Moreno, P., Curado, N., López Serrano, J. y Rodríguez Iglesias, M.A. (2016). Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex. Chemical Communications, 52, 2114-2117.
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URI: https://hdl.handle.net/11441/79062

DOI: 10.1039/C5CC09650B

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