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Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions

Opened Access Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions

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Autor: Biffis, Andrea
Tubaro, Cristina
Scattolin, Elena
Basato, Marino
Papini, Grazia
Santini, Carlo
Álvarez González, Eleuterio
Conejero Iglesias, Salvador
Fecha: 2009
Publicado en: Dalton Transactions, 35, 7223-7229.
Tipo de documento: Artículo
Resumen: Novel synthetic routes for the preparation of trinuclear copper(I) complexes with triscarbene ligands are presented, which yield higher purity products than the one previously described. The first crystal structure of one of these complexes is reported and confirms the expected structure. The trinuclear complexes proved to be efficient catalysts of Ullmann-type reactions as well as of the Sonogashira reaction.
Cita: Biffis, A., Tubaro, C., Scattolin, E., Basato, M., Papini, G., Santini, C.,...,Conejero Iglesias, S. (2009). Trinuclear copper(I) complexes with triscarbene ligands: catalysis of C–N and C–C coupling reactions. Dalton Transactions, 35, 7223-7229.
Tamaño: 246.3Kb
Formato: PDF

URI: https://hdl.handle.net/11441/72038

DOI: 10.1039/B906730B

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