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A Potentiometric Evaluation of Stability Constants of Two-Step Overlapping Equilibria via a Bilogarithmic Hyperbolic Cosine Method

 

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Opened Access A Potentiometric Evaluation of Stability Constants of Two-Step Overlapping Equilibria via a Bilogarithmic Hyperbolic Cosine Method
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Author: Beaumont, Samuel
Martín Bueno, Julia
García Asuero, Agustín
Department: Universidad de Sevilla. Departamento de Química Analítica
Date: 2016
Published in: Analytical sciences, 6, 33-43.
Document type: Article
Abstract: A bilogarithmic hyperbolic cosine method for the evaluation of overlapping formation constants at varying (or fixed) ionic strength is devised in this paper and applied to data reported in the analytical literature, i.e. succinic acid system, Cu(II)-glycine system and Ag(I)-aminobutan -1-ol system. The method is based on the linearization of the formation function ñ = f(pH) or ñ = f(pL) data. A theoretical slope of unity should be obtained thus proving the correctness of the assumed equilibria. An additional advantage of the bilogarithmic method proposed is that it provides a closed scale representation of Y and X unlike other plots. This paper forms part of an investigation into the uses of bilo garithmic methods and hyperbolic functions in parameter estimation. Methods based on the application of spectrophotometric measurements have been the subject of recent studies.
Cite: Beaumont, S., Martín Bueno, J. y García Asuero, A. (2016). A Potentiometric Evaluation of Stability Constants of Two-Step Overlapping Equilibria via a Bilogarithmic Hyperbolic Cosine Method. Analytical sciences, 6, 33-43.
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URI: http://hdl.handle.net/11441/67805

DOI: 10.4236/jasmi.2016.62005

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