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A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles

dc.creatorMartínez Prieto, Luis Migueles
dc.creatorUrbaneja, C.es
dc.creatorPalma Ramírez, María del Pilares
dc.creatorCámpora Pérez, Juanes
dc.creatorPhilippot, Karinees
dc.creatorChaudret, Brunoes
dc.date.accessioned2017-11-23T17:24:52Z
dc.date.available2017-11-23T17:24:52Z
dc.date.issued2015
dc.identifier.citationMartínez Prieto, L.M., Urbaneja, C., Palma, P., Cámpora, J., Philippot, K. y Chaudret, B. (2015). A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles. Chemical Communications, 51, 4647-4650.
dc.identifier.issn1359-7345 (impreso)es
dc.identifier.issn1364-548X (electrónico)es
dc.identifier.urihttp://hdl.handle.net/11441/66567
dc.description.abstractThe betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the metal surface takes place through the carbodiimide moiety. The resulting RuNPs led to decarbonylation of THF and showed size selectivity for styrene hydrogenation.es
dc.description.sponsorshipJunta de Andalucía CTQ2012-30962, FQM6276es
dc.description.sponsorshipEuropean Union NANOSONWINGS 2009-246763es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofChemical Communications, 51, 4647-4650.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleA betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticleses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Inorgánicaes
dc.relation.projectIDCTQ2012-30962es
dc.relation.projectIDFQM6276es
dc.relation.projectIDNANOSONWINGS 2009-246763es
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C5CC00211Ges
dc.identifier.doi10.1039/C5CC00211Ges
idus.format.extent4 p.es
dc.journaltitleChemical Communicationses
dc.publication.volumen51es
dc.publication.initialPage4647es
dc.publication.endPage4650es
dc.contributor.funderJunta de Andalucía
dc.contributor.funderEuropean Union (UE)

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