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A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles

 

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Opened Access A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles
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Author: Martínez Prieto, Luis Miguel
Urbaneja, C.
Palma Ramírez, María del Pilar
Cámpora Pérez, Juan
Philippot, Karine
Chaudret, Bruno
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2015
Published in: Chemical Communications, 51, 4647-4650.
Document type: Article
Abstract: The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the metal surface takes place through the carbodiimide moiety. The resulting RuNPs led to decarbonylation of THF and showed size selectivity for styrene hydrogenation.
Cite: Martínez Prieto, L.M., Urbaneja, C., Palma, P., Cámpora, J., Philippot, K. y Chaudret, B. (2015). A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles. Chemical Communications, 51, 4647-4650.
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URI: http://hdl.handle.net/11441/66567

DOI: 10.1039/C5CC00211G

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