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β-Hydrogen Elimination Reactions of Nickel and Palladium Methoxides Stabilised by PCP Pincer Ligands

 

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Opened Access β-Hydrogen Elimination Reactions of Nickel and Palladium Methoxides Stabilised by PCP Pincer Ligands
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Author: Martínez Prieto, Luis Miguel
Ávila, Elena
Palma Ramírez, María del Pilar
Álvarez González, Eleuterio
Cámpora Pérez, Juan
Date: 2015
Published in: Chemistry - a European Journal, 21 (27), 9833-9849.
Document type: Article
Abstract: Nickel and palladium methoxides [((iPr)PCP)M-OMe], which contain the (iPr)PCP pincer ligand, decompose upon heating to give products of different kinds. The palladium derivative cleanly gives the dimeric Pd(0) complex [Pd(μ-(iPr)PCHP)]2 ((iPr)PCHP =...
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Cite: Martínez Prieto, L.M., Ávila, E., Palma, P., Álvarez González, E. y Cámpora, J. (2015). β-Hydrogen Elimination Reactions of Nickel and Palladium Methoxides Stabilised by PCP Pincer Ligands. Chemistry - a European Journal, 21 (27), 9833-9849.
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URI: http://hdl.handle.net/11441/65616

DOI: 10.1002/chem.201500652

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