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Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic M(III) Alkylidenes

 

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Opened Access Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic M(III) Alkylidenes
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Author: Campos, Jesús
Carmona Guzmán, Ernesto
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2015
Published in: Organometallics, 34, 2212-2221.
Document type: Article
Abstract: Cyclometalated chloride complexes of rhodium and iridium based on (5-C5Me5)M(III) fragments that result from the metalation of the xylyl substituent of a coordinated PR2(Xyl) phosphine (Xyl=2,6-Me2C6H3) have been prepared by reaction of the appropr...
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Cite: Campos, J. y Carmona Guzmán, E. (2015). Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic M(III) Alkylidenes. Organometallics, 34, 2212-2221.
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Format: PDF

URI: http://hdl.handle.net/11441/65578

DOI: 10.1021/om500910t

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