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(Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN 2)hydro­borato]iridium(III)

Opened Access (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN 2)hydro­borato]iridium(III)

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Autor: Gómez, Margarita
López Santos, Laura
Paneque Sosa, Margarita
Mereiter, Kurt
Departamento: Universidad de Sevilla. Departamento de Química Inorgánica
Fecha: 2013
Publicado en: Acta Crystallographica Section E: Structure Reports Online, 69 (5), 1-13.
Tipo de documento: Artículo
Resumen: In the mononuclear title iridium(III) complex, [Ir(C4H8)(C15H22BN6)(C3H9P)], which is based on the [tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium moiety, Ir[TpMe2], the IrIII atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethyl­phosphane ligand in a modestly distorted octa­hedral coordination environment formed by three facial N, two C and one P atom. The iridium–butane-1,4-diyl ring has an envelope conformation. This ring is disordered because alternately the second or the third C atom of the butane-1,4-diyl fragment function as an envelope flap atom (the occupancy ratio is 1:1). In the crystal, mol­ecules are organized into densely packed columns extending along [101]. Coherence between the mol­ecules is essentially based on van der Waals inter­actions.
Cita: Gómez, M., López Santos, L., Paneque Sosa, M. y Mereiter, K. (2013). (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN 2)hydro­borato]iridium(III). Acta Crystallographica Section E: Structure Reports Online, 69 (5), 1-13.
Tamaño: 451.7Kb
Formato: PDF

URI: http://hdl.handle.net/11441/63988

DOI: 10.1107/S1600536813008040

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