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Stereoselective synthesis of chiral furan amino acid analogues of D- and L-serine from D-sugars

 

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Opened Access Stereoselective synthesis of chiral furan amino acid analogues of D- and L-serine from D-sugars
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Author: Molina, Lidia
Moreno Vargas, Antonio José
Carmona Asenjo, Ana Teresa
Robina Ramírez, Inmaculada
Department: Universidad de Sevilla. Departamento de Química orgánica
Date: 2006
Document type: Article
Abstract: The synthesis of chiral furan amino acid analogues of D - and L -serine is reported. The developed methodology starting from D -xylose affords the corresponding amino acid derivative analogue of D -serine enantiomerically pure. Starting from D -arabinose, the corresponding analogue of L -serine was isolated in 92.3% enantio- meric purity. The analogue of D -serine was transformed into a stable Fmoc activated derivative ready to be incorporated into peptides.
Size: 80.41Kb
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URI: http://hdl.handle.net/11441/63355

DOI: 10.1055/s-2006-941570

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