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Role of the A 1 3 Allylic lnteraction on the Stereochemistry of Formation of Schiff's Bases derived from Bicyclo[2.2.1 ]hept-5-en-2-one and 7-Oxabicyclo[2.2.1] hept-5-en-2-one

Opened Access Role of the A 1 3 Allylic lnteraction on the Stereochemistry of Formation of Schiff's Bases derived from Bicyclo[2.2.1 ]hept-5-en-2-one and 7-Oxabicyclo[2.2.1] hept-5-en-2-one

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Autor: Arjona, Odón
Mallo, Araceli
Manzano, Cristina
Plumet, Joaquín
Galbis Pérez, Juan Antonio
Jaime, Carlos
Departamento: Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica
Fecha: 1988
Publicado en: Journal of the Chemical Society, Perkin Transactions 2, 6, 965-868.
Tipo de documento: Artículo
Resumen: The stereochemistry of formation of Schiff′s bases de rived from norbornen-2-one and 7-oxanorbornen-2-one has been studied by1H and13C n.m.r. spectroscopy. Elucidation of the reason for the preference for the £-isomer in both cases has been attempted by molecular mechanics calculations. This preference may be justified by A1,3 allylic interactions.
Cita: Arjona, O., Mallo, A., Manzano, C., Plumet, J., Galbis Pérez, J.A. y Jaime, C. (1988). Role of the A 1 3 Allylic lnteraction on the Stereochemistry of Formation of Schiff's Bases derived from Bicyclo[2.2.1 ]hept-5-en-2-one and 7-Oxabicyclo[2.2.1] hept-5-en-2-one. Journal of the Chemical Society, Perkin Transactions 2, 6, 965-868.
Tamaño: 488.0Kb
Formato: PDF

URI: http://hdl.handle.net/11441/45398

DOI: http;//dx.doi.org/10.1039/P29880000865

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