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Artículo
New insights on the kinetic analysis of isothermal data: The independence of the activation energy from the assumed kinetic model
(American Chemical Society, 2015)
Isothermal experiments are widely employed to study the kinetics of solid-state reactions or processes to extract essential kinetic information needed for modeling the processes at an industrial scale. The kinetic analysis ...
Artículo
Limitations of model-fitting methods for kinetic analysis: Polystyrene thermal degradation
(Elsevier, 2013)
In this paper, some clarifications regarding the use of model-fitting methods of kinetic analysis are provided in response to the lack of plot linearity and dispersion in the activation energy values for the thermal ...