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Artículo
β-Hydrogen Elimination Reactions of Nickel and Palladium Methoxides Stabilised by PCP Pincer Ligands
(John Wiley & Sons, 2015)
Nickel and palladium methoxides [((iPr)PCP)M-OMe], which contain the (iPr)PCP pincer ligand, decompose upon heating to give products of different kinds. The palladium derivative cleanly gives the dimeric Pd(0) complex ...
Artículo
Synthesis and Reactivity of Nickel an Palladium Fluoride Complexes with PCP Pincer Ligands. A NMR-Based Assessment of Electron-Donating Properties of Fluoride and Other Monoanionic Ligands
(American Chemical Society, 2012)
A series of complexes of the type [(iPrPCP)M-L] (M = Ni, Pd), containing the 2,6-bis(diisopropylphosphinomethyl)phenyl (iPrPCP) pincer ligand and simple monoanionic ligands L (F, Cl, Br, H, Me, Ph, NO3, and OTf), have been ...
Artículo
Organometallic Nanoparticles Ligated by NHCs: Synthesis, Surface Chemistry and Ligand Effects
(MDPI, 2020)
Over the last 20 years, the use of metallic nanoparticles (MNPs) in catalysis has awakened a great interest in the scientific community, mainly due to the many advantages of this kind of nanostructures in catalytic ...
Artículo
A betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce ultra-small ruthenium nanoparticles
(Royal Society of Chemistry, 2015)
The betaine adduct of N-heterocyclic carbene and carbodiimide (ICy·(p-tol)NCN) was found to be a very efficient ligand to prepare very small (1–1.3 nm) ruthenium nanoparticles (RuNPs). The coordination of the ligand on the ...
Artículo
Palladium(II) carboxylates and palladium(I) carbonyl carboxylate complexes as catalysts for olefin cyclopropanation with ethyl diazoacetate
(Royal Society of Chemistry (Great Britain), 2009)
Palladium(I) carbonyl carboxylate complexes [Pd(μ-CO)(μ-RCO2)]n (R = Me, n = 4; R = CMe3, n = 6) and the corresponding palladium(II) carboxylates (acetate and pivalate) catalyze the cyclopropanation of olefins with ethyl ...
Artículo
Nickel and Palladium Complexes with Reactive σ-Metal-Oxygen Covalent Bonds
(Wiley-Blackwell, 2020)
This article reviews the chemistry of nickel and palladium complexes with terminally bound hydroxide and alkoxide ligands. The research carried out in our group is discussed in the context of the general literature. It is ...
Artículo
Zwitterionic amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts
(Royal Society of Chemistry, 2017)
Ligand control of metal nanoparticles (MNPs) is rapidly gaining importance as ligands can stabilize the MNPs and regulate their catalytic properties. Herein we report the first example of Pt NPs ligated by imidazoliumamidinate ...
Artículo
Monomeric alkoxide and alkylcarbonate complexes of nickel and palladium stabilized with the iPrPCP pincer ligand: a model for the catalytic carboxylation of alcohols to alkyl carbonates
(Royal Society of Chemistry, 2019)
Monomeric alkoxo complexes of the type [(iPrPCP)M-OR] (M = Ni or Pd; R = Me, Et, CH2CH2OH; iPrPCP = 2,6-bis(diisopropylphosphino)phenyl) react rapidly with CO2 to afford the corresponding alkylcarbonates [(iPrPCP)M-OCOOR]. ...