Listar Artículos (Química Inorgánica) por autor "Álvarez González, Eleuterio"
Mostrando ítems 1-20 de 41
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1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap
Haldón, Estela; Álvarez González, Eleuterio; Nicasio Jaramillo, María del Carmen; Pérez, Pedro J. (Royal Society of Chemistry, 2014)Electron deficient azides are challenging substrates in CuAAC reactions. Particularly, when N-carbonyl azides are applied ...
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A Diels–Alder Reaction Triggered by a [4 + 3] Metallacycloaddition
Vivancos Ureña, Ángela; Vattier Lagarrigue, María Florencia; López Serrano, Joaquín; Paneque Sosa, Margarita; López Poveda, Manuel; Álvarez González, Eleuterio (American Chemical Society, 2015)The TpMe2Ir(III) complex 1-OH2 (TpMe2 = hydrotris(3,5-dimethylpyrazolyl)borate), which contains a labile molecule of water ...
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A versatile approach to access trimetallic complexes based on trisphosphinite ligands
Miranda Pizarro, Juan; González Alférez, Macarena; Fernández Martínez, María Dolores; Álvarez González, Eleuterio; Maya Díaz, Celia María; Campos Manzano, Jesús (Multidisciplinary Digital Publishing Institute (MDPI), 2020)A straightforward method for the preparation of trisphosphinite ligands in one step, using only commercially available ...
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Activation of Small Molecules by the Metal-Amido Bond of Rhodium(III) and Iridium(III) (η5-C5Me5)M-Aminopyridinate Complexes
Zamorano Márquez, Ana; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto (American Chemical Society, 2018)We report the synthesis and structural characterization of five-coordinate complexes of rhodium and iridium of the type ...
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Aluminium(iii) dialkyl 2,6-bisimino-4R-dihydropyridinates(−1): selective synthesis, structure and controlled dimerization
Gallardo Villagrán, Manuel; Vidal Barrero, Fernando; Palma Ramírez, María del Pilar; Álvarez González, Eleuterio; Chen, Eugene Y. X.; Cámpora Pérez, Juan (Royal Society of Chemistry, 2019)A family of stable and otherwise selectively unachievable 2,6-bisimino-4-R-1,4-dihydropyridinate aluminium (III) dialkyl ...
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Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes
Ortega Lepe, Isabel; Rossin, Andrea; Sánchez Mellado, Práxedes; López Santos, Laura; Rendón Márquez, Nuria; Álvarez González, Eleuterio; López Serrano, Joaquín; Suárez Escobar, Andrés Luis (American Chemical Society, 2021)Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving ...
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Antimicrobial Properties of Amino-Acid-Derived N-Heterocyclic Carbene Silver Complexes
Sánchez, Adrián; Carrasco Carrasco, Carlos Jesús; Montilla Ramos, Francisco Javier; Álvarez González, Eleuterio; Galindo del Pozo, Agustín; Pérez Aranda, María; Pajuelo Domínguez, Eloísa; Alcudia Cruz, Ana (MDPI, 2022)Complexes {Ag[NHCMes,R]}n (R = H, 2a; Me, 2b and 2b’; iPr, 2c; iBu, 2d), were prepared by treatment of imidazolium precursor ...
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Chirality influence on the cytotoxic properties of anionic chiral bis(N-heterocyclic carbene)silver complexes
Carrasco Carrasco, Carlos Jesús; Montilla Ramos, Francisco Javier; Álvarez González, Eleuterio; Calderón Montaño, José Manuel; López Lázaro, Miguel; Galindo del Pozo, Agustín (Elsevier, 2022)Complexes Na3[Ag(NHCR)2], 2a-e and 2b’-c’, where NHCR is a N-heterocyclic carbene of the 2,2′-(1H-2λ3,3λ4-imidazole-1,3-diyl)dicarboxylate ...
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Different coordination modes of an aryl-substituted hydrotris(pyrazolyl) borate ligand in rhodium and iridium complexes
Conejero Iglesias, Salvador; Esqueda Oliva, Ana Cristina; Valpuesta, José Enrique V.; Álvarez González, Eleuterio; Maya Díaz, Celia María; Carmona Guzmán, Ernesto (Elsevier, 2011)Complexes TptolRh(C2H4)2 (1a) and TptolRh(CH2C(Me)C(Me)CH2) (1b) have been prepared by reaction of KTptol with the appropriate ...
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Epimerization of glucose over ionic liquid/phosphomolybdate hybrids: structure-activity relationship
Megías Sayago, Cristina; Álvarez González, Eleuterio; Ivanova, Svetlana; Odriozola Gordón, José Antonio (Royal Society of Chemistry, 2018)The influence of the crystal structure and chemical nature of some ionic liquid/phosphomolybdate hybrids on their catalytic ...
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Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
Marín Gómez, Mario; Moreno Díaz, Juan José; Alcaide, María M.; Álvarez González, Eleuterio; López Serrano, Joaquín; Campos Manzano, Jesús; Nicasio Jaramillo, María del Carmen; Carmona Guzmán, Ernesto (Elsevier, 2019)The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ...
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Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands
Carrasco, Mario; Mendoza, Irene; Álvarez González, Eleuterio; Grirrane, Abdessamad; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; Falceto, Andrés; Álvarez, Santiago; Carmona Durán, Ernesto (Wiley, 2015)To clarify the nature of the Mo[BOND]Carene interaction in terphenyl complexes with quadruple Mo[BOND]Mo bonds, ether ...
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Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2
Cristóbal Gasga, Crispín Silvano; Álvarez González, Eleuterio; Paneque Sosa, Margarita; López Poveda, Manuel (American Chemical Society, 2013)The Ir(III) pyridylidene TpMe2tiebar above startr(CH2CH2-o-tiebar above endC6H4)(tiebar above startCN(H)CHCHCHtiebar above ...
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Functionalization of 3-Iridacyclopentenes
Gómez González, Margarita; Rendón Márquez, Nuria; Álvarez González, Eleuterio; Mereiter, Kurt; López Poveda, Manuel; Paneque Sosa, Margarita; Wolffrearrangement (Wiley, 2017)Members of a series of iridacyclopentenes of composition [TpMe2Ir(k2-C,C-CH2CR′=CRCH2)(CO)] (TpMe2=hydrotris(3,5-dimethylpyrazolyl)borate; ...
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Halide encapsulation by dicarboxylate oxido-vanadium cage complexes
Gómez, Margarita; Pastor Navarro, Antonio; Álvarez González, Eleuterio; Olloqui Sariego, José Luis; Galindo del Pozo, Agustín (The Royal Society of Chemistry, 2018)Compounds [Bu4N]2[V8O16(oda)4⊂2Cl], 1, [Bu4N]2[V8O16(glut)4⊂2Cl], 2, and [Bu4N][V4O8(glut)2⊂F], 3, (oda = oxydiacetate, ...
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Homochiral imidazolium-based dicarboxylate silver(i) compounds: synthesis, characterisation and antimicrobial properties
Carrasco Carrasco, Carlos Jesús; Montilla Ramos, Francisco Javier; Álvarez González, Eleuterio; Galindo del Pozo, Agustín; Pérez Aranda, María; Pajuelo Domínguez, Eloísa; Alcudia Cruz, Ana (Royal Society of Chemistry, 2022-03)Complexes [Ag(LR)], 2 (LR = 2,2′-(imidazolium-1,3-diyl)di(2-alkylacetate)), were prepared by treatment of compounds HLR, ...
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Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity
Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the hydroboration of ...
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Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment
Hernández Juárez, Martín; López Serrano, Joaquín; González Herrero, P.; Rendón Márquez, Nuria; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)An iridium complex featuring a metalated lutidine-derived CNP ligand reacts with KOt Bu to yield a dimeric species with ...
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Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; López Santos, Laura; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2020)Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts ...
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Influence of N-donor bases and the solvent in oxodiperoxomolybdenum catalysed olefin epoxidation with hydrogen peroxide in ionic liquids
Herbert, Matthew; Montilla Ramos, Francisco Javier; Galindo del Pozo, Agustín; Moyano López, Raquel; Pastor Navarro, Antonio; Álvarez González, Eleuterio (Royal Society of Chemistry, 2011)Biphasic catalytic olefin epoxidation systems consisting of oxodiperoxomolybdenum catalysts in 1- n -alkyl-3-methylimidazolium ...