2023-04-112023-04-112023Román Hidalgo, C., Martín Valero, M.J., López Pérez, G. y Villar Navarro, M. (2023). Green Method for the Selective Electromembrane Extraction of Parabens and Fluoroquinolones in the Presence of NSAIDs by Using Biopolymeric Chitosan Films. Membranes, 13 (3), 326. https://doi.org/10.3390/membranes13030326.2077-0375https://hdl.handle.net/11441/144176A chitosan biopolymeric membrane was successfully used as a support in a green elec- tromembrane extraction procedure for the simultaneous and selective extraction of seven parabens and three fluoroquinolones in the presence of three non-steroidal anti-inflammatory drugs. The optimal experimental conditions (10 mL donor phase and 50 μL acceptor phase, pH 10 in both phases; 80 V of applied voltage during 15 min of extraction time) were determined, providing high enrichment factors for six of the studied parabens (EF ≥ 90) and the three fluoroquinolones ( EF ≥ 50 ). Wide linear concentration ranges (0.5–500 μg L−1), good linearity (>97%), low limits of detection (0.2–1.1 μg L−1), and good repeatability (relative standard deviation values 4–10%) were achieved. The proposed method was successfully applied for the extraction of the target analytes from different kinds of water samples (river, lake, and swimming pool). The usage of a chitosan membrane in the extraction process presents many advantages, as it is a biodegradable and versatile support, offering a good alternative to commercial plastic materials commonly used in this methodology and these procedures.application/pdf14 p.engAtribución 4.0 Internacionalhttp://creativecommons.org/licenses/by/4.0/ParabensFluoroquinolonesNSAIDsChitosanElectromembrane extractioninfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccess10.3390/membranes13030326