2025-02-212025-02-212024-08-05Manchón Gordon, A.F., Lobo-Llamas, C., Molina Molina, S., Perejón Pazo, A., Sánchez-Jiménez, P.E. y Pérez-Maqueda, L.A. (2024). Influence of the atmosphere on the formation of high-entropy oxides within the Co–Cu–Fe–Mg–Mn–Ni–O system via reactive flash sintering. Ceramics International, 50 (21), 42276-42285. https://doi.org/10.1016/j.ceramint.2024.08.073.0272-88421873-3956https://hdl.handle.net/11441/169176In this study, the feasibility of preparing quinary equimolar high-entropy oxides within the Co–Cu–Fe–Mg–Mn–Ni–O system was explored using the reactive flash sintering (RFS) technique. Various compositions were tested using this technique under atmosphere pressure, leading to the formation of two primary phases: rock-salt and spinel. Conversely, a new high-entropy oxide was produced as a single-phase material with the composition (Co0.2,Cu0.2,Mg0.2,Mn0.2,Ni0.2)O when RFS experiments were conducted in nitrogen atmosphere. The reducing conditions achieved in nitrogen enabled the incorporation of cations with oxidation states different from +2 into the rock-salt lattice, emphasizing the critical role of the processing atmosphere, whether inert or oxidizing, in the formation of high-entropy oxides. The electrical characterization of this material was obtained via impedance spectroscopy, exhibiting a homogeneous response attributed to electronic conduction with a temperature dependence characteristic of disordered systems.application/pdf9engAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Reactive flash sintering High-entropy oxides Rock-salt structure Impedance spectroscopyinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccesshttps://doi.org/10.1016/j.ceramint.2024.08.073