2023-03-062023-03-062022Santamaría Gallardo, N., Velasco, C., Marín Gómez, ., Maya Díaz, C.M. y Nicasio Jaramillo, M.d.C. (2022). LPdCl2(amine) Complexes Supported by Terphenyl Phosphanes: Applications in Aryl Amination Reactions. Dalton Transactions, 51 (41), 15734-15740. https://doi.org/10.1039/d2dt01354a.1477-92261477-9234https://hdl.handle.net/11441/143183Despite the excellent catalytic properties display by NHC-Pd-PEPPSI complexes in cross-coupling, phosphane analogs have been barely screened. In this work, we report the synthesis and characterization of a series of LPdCl2(amine) complexes bearing dialkylterphenyl phosphanes (PR2Ar′) and pyridine or morpholine ligands. The novel compounds have been tested as precatalysts in aryl amination reactions. The complex [(PCyp2ArXyl2)PdCl2(morpholine)] shows the best catalytic activity allowing the room-temperature coupling of aryl bromides and chlorides with aniline.application/pdf7 p.engAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccess10.1039/d2dt01354a