Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands

Sánchez Mellado, PráxedesHernández Juárez, MartínRendón Márquez, NuriaLópez Serrano, JoaquínLópez Santos, LauraÁlvarez González, EleuterioPaneque Sosa, MargaritaSuárez Escobar, Andrés Luis2022-09-132022-09-132020Sánchez Mellado, P., Hernández Juárez, M., Rendón Márquez, N., López Serrano, J., López Santos, L., Álvarez González, E.,...,Suárez Escobar, A.L. (2020). Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands. Dalton Transactions, 49 (28), 9583-9587. https://10.1039/d0dt02326d.1477-9234https://hdl.handle.net/11441/136998Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts in the hydrogenation and dehydrogenation of N-heterocycles. Reaction of a Ru-CNN(H) complex with an excess of base produces the formation of a Ru(0) derivative, which is observed under catalytic conditions.application/pdf5 p.engAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligandsinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccesshttps://doi.org/10.1039/d0dt02326d