Scheuermann, Margaret L.Grice, Kyle A.Ruppel, Matthew J.Roselló Merino, MartaKaminsky, WernerGoldberg, Karen I.2018-01-092018-01-092014Scheuermann, M.L., Grice, K.A., Ruppel, M.J., Roselló Merino, M., Kaminsky, W. y Goldberg, K.I. (2014). Hemilability of P(X)N-type ligands (X = O, N–H): rollover cyclometalation and benzene C–H activation from (P(X)N)PtMe2 complexes. Dalton Transactions, 43, 12018-.1477-9226 (impreso)1477-9234 (electrónico)http://hdl.handle.net/11441/68544The thermolyses of (tBuP(O)N)PtMe2 (1, tBuP(O)N = (di-tert-butylphosphinito)pyridine) and (tBuP(N–H)N)PtMe2 (3, tBuP(N–H)N = (di-tert-butylphosphino)-2-aminopyridine) in benzene-d6 were investigated. With (tBuP(O) N)PtMe2, the product of a rollover cyclometalation of the pyridyl ring was observed in 80% yield along with formation of CH4. In contrast, thermolysis of (tBuP(N–H)N)PtMe2 resulted in competing rollover cyclometalation and intermolecular benzene C–H activation with production of a mixture of CH4 and CH3Dapplication/pdfengAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccesshttps://doi.org/10.1039/c4dt01143k