Galindo del Pozo, AgustínCarmona Durán, ErnestoPérez, Pedro J.Álvarez, María2020-03-052020-03-052019Galindo del Pozo, A., Carmona Durán, E., Pérez, P.J. y Álvarez, M. (2019). Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands. Chemical Science, 10, 8541-8546.2041-6539https://hdl.handle.net/11441/93916The first examples of stable metal complexes with coordinated ethylene and carbon dioxide ligands are reported. Reaction of tris(ethylene) complexes mer-M(C2H4)3(PNP) (M = Mo and W; PNP = 2,6-bis(diphenylphosphinomethyl)pyridine) with CO2 yields the corresponding, mixed cis-M(C2H4)2(CO2)(PNP) derivatives. X-ray studies reveal six-coordinate structures exhibiting η2-ethylene and κ2-C,O carbon dioxide coordination. Remarkably, the formation of the molybdenum CO2 adduct occurs also in the solid state at room temperature, under 4 bar of CO2, in a nearly quantitative manner.application/pdfengAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Molybdenum and tungsten complexes with carbon dioxide and ethylene ligandsinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccesshttps://doi.org/10.1039/c9sc03225h