Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes

2023-04-042023-04-042018Fernández Cestau, J., Rocchigiani, L., Pintus, A., Jiménez Rama, R., Budzelaar, P.H.M. y Bochmann, M. (2018). Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes. Chemical Communications, 54 (81), 11447-11450. https://doi.org/10.1039/c8cc06409a.1359-73451364-548Xhttps://hdl.handle.net/11441/143913Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by isocyanide in sufficient excess to trap the Au(II) intermediateapplication/pdf4 p.engAttribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/Isocyanide insertion into Au-H bonds: first gold iminoformyl complexesinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/openAccess10.1039/c8cc06409a