Article
Direct evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexes
Author/s | Cartes Domínguez, María Ángeles
Rodríguez Delgado, Antonio Palma Ramírez, María del Pilar Sánchez Fernández, Luis Cámpora Pérez, Juan |
Department | Universidad de Sevilla. Departamento de Química Inorgánica |
Publication Date | 2014 |
Deposit Date | 2018-01-03 |
Published in |
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Abstract | 1H NMR studies on ethylene oligomerization catalysed by the neutral monoalkyl complex [Fe(Me)(iPrBIP)] allow direct observation of alkyl iron intermediates as well as reversible ethylene coordination to the metal center, ... 1H NMR studies on ethylene oligomerization catalysed by the neutral monoalkyl complex [Fe(Me)(iPrBIP)] allow direct observation of alkyl iron intermediates as well as reversible ethylene coordination to the metal center, providing for the first time experimental evidence for a coordination-insertion mechanism of iron-catalysed ethylene upgrade reactions. |
Funding agencies | Ministerio de Economía y Competitividad (MINECO). España Junta de Andalucía |
Project ID. | CTQ2012-30962
FQM5074 |
Citation | Cartes Domínguez, M.Á., Rodríguez Delgado, A., Palma Ramírez, M.d.P., Sánchez Fernández, L. y Cámpora Pérez, J. (2014). Direct evidence for a coordination-insertion mechanism of ethylene oligomerization catalysed by neutral 2,6-bisiminopyridine iron monoalkyl complexes. Catalysis Science and Technology, 4, 2504-2507. |
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