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Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes

dc.creatorFrancos, Javieres
dc.creatorGrande Carmona, Franciscaes
dc.creatorFaustino, Hélioes
dc.creatorIglesias Sigüenza, Francisco Javieres
dc.creatorDíez Martín, Elenaes
dc.creatorAlonso, Isaaces
dc.creatorFernández Fernández, Rosario Fátimaes
dc.creatorLassaletta, José M.es
dc.creatorLópez, Fernandoes
dc.creatorMascareñas, José L.es
dc.date.accessioned2022-11-11T17:56:32Z
dc.date.available2022-11-11T17:56:32Z
dc.date.issued2012
dc.identifier.citationFrancos, J., Grande Carmona, F., Faustino, H., Iglesias Sigüenza, F.J., Díez Martín, E., Alonso, I.,...,Mascareñas, J.L. (2012). Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes. Journal of the American Chemical Society, 134 (35), 14322-14325. https://doi.org/10.1021/ja3065446.
dc.identifier.issn0002-7863es
dc.identifier.issn1520-5126es
dc.identifier.urihttps://hdl.handle.net/11441/139339
dc.description.abstractThe first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and dienes is reported. The reaction provides good yields of optically active cyclohexenes featuring diverse substitution patterns and up to three stereocenters. Key to the success of the process is the use of newly designed axially chiral N-heterocyclic carbene-gold catalysts.es
dc.description.sponsorshipMinisterio de Economía y Competitividad SAF2010-20822-C02, CTQ2010-15297, CTQ2010-14974, CSD2007-00006es
dc.description.sponsorshipXunta de Galicia INCITE09209084PR, GRC2010/12es
dc.description.sponsorshipJunta de Andalucía 2008/FQM-3833, 2009/FQM-4537es
dc.description.sponsorshipFundação para a Ciência e a Tecnologia SFRH/BD/60214/2009es
dc.formatapplication/pdfes
dc.format.extent4 p.es
dc.language.isoenges
dc.publisherAmerican Chemical Societyes
dc.relation.ispartofJournal of the American Chemical Society, 134 (35), 14322-14325.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleAxially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dieneses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química orgánicaes
dc.relation.projectIDSAF2010-20822-C02es
dc.relation.projectIDCTQ2010-15297es
dc.relation.projectIDCTQ2010-14974es
dc.relation.projectIDCSD2007-00006es
dc.relation.projectIDINCITE09209084PRes
dc.relation.projectIDGRC2010/12es
dc.relation.projectID2008/FQM-3833es
dc.relation.projectID2009/FQM-4537es
dc.relation.projectIDSFRH/BD/60214/2009es
dc.relation.publisherversionhttps://dx.doi.org/10.1021/ja3065446es
dc.identifier.doi10.1021/ja3065446es
dc.journaltitleJournal of the American Chemical Societyes
dc.publication.volumen134es
dc.publication.issue35es
dc.publication.initialPage14322es
dc.publication.endPage14325es
dc.contributor.funderMinisterio de Economía y Competitividad (MINECO). Españaes
dc.contributor.funderXunta de Galiciaes
dc.contributor.funderJunta de Andalucíaes
dc.contributor.funderFundação para a Ciência e a Tecnologia. Portugales

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