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Now showing items 1-10 of 12
Article
Study of the dehydroxylation-rehydroxylation of pyrophyllite
(American Ceramic Society, 2010)
Pyrophyllite is a raw material of significant interest due to its large number of applications. Most of these applications require a thermal transformation of pyrophyllite; this thermal transformation implies the release ...
Article
Hydration and carbonation reactions of calcium oxide by weathering: Kinetics and changes in the nanostructure
(Elsevier, 2015)
The weathering reactions of hydration and carbonation of nanostructured calcium oxide with atmospheric moisture and carbon dioxide have been characterized. This work is the first-to-date combined kinetic and nanostructural ...
Article
Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis
(Elsevier, 2013)
The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators during the last decades, the actual understanding of the thermal decomposition kinetics is still very ...
Article
Gold supported on CuOx/CeO2 catalyst for the purification of hydrogen by the CO preferential oxidation reaction (PROX)
(Elsevier, 2014)
Hydrogen produced from the conversion of hydrocarbons or alcohols contains variable amounts of CO that should be removed for some applications such as feeding low-temperature polymer electrolyte membrane fuel cells (PEMFCs). ...
Article
Combined kinetic analysis of thermal degradation of polymeric materials under any thermal pathway
(Elsevier, 2009)
Combined kinetic analysis has been applied for the first time to the thermal degradation of polymeric materials. The combined kinetic analysis allows the determination of the kinetic parameter from the simultaneous ...
Article
Constant rate thermal analysis for thermal stability studies of polymers
(Elsevier, 2011)
This paper explores the relationship between the shapes of temperature-time curves obtained from experimental data recorded by means of constant rate thermal analysis (CRTA) and the kinetic model followed by the thermal ...
Article
Constant rate thermal analysis of a dehydrogenation reaction
(Royal Society of Chemistry, 2016)
The Constant Rate Thermal Analysis (CRTA) procedure has been employed for the first time to study the kinetics of MgH2 dehydrogenation by thermogravimetry under high vacuum. CRTA implies controlling the temperature in such ...
Article
A Promising approach to the kinetics of crystallization processes: The sample controlled thermal analysis
(American Ceramic Society, 2017)
Constant Rate Thermal Analysis (CRTA) method implies controlling the temperature in such a way that the reaction rate is maintained constant all over the process. This method allows determining simultaneously both the ...
Article
Kinetic model for thermal dehydrochlorination of poly(vinyl chloride)
(Elsevier, 2010)
In this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal dehydrochlorination of two different samples of PVC. It has been observed that this dehydrochlorination ...
Article
Combined TGA-MS kinetic analysis of multistep processes. Thermal decomposition and ceramification of polysilazane and polysiloxane preceramic polymers.
(2016)
The polymer-to-ceramic transformation kinetics of two widely employed ceramic precursors; 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane (TTCS) and polyureamethylvinylsilazane (CERASET) have been investigated ...