ListarArtículos (Instituto de Investigaciones Químicas (IIQ) – CIC Cartuja) por materia "Rhodium"
Mostrando ítems 1-5 de 5
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Different coordination modes of an aryl-substituted hydrotris(pyrazolyl) borate ligand in rhodium and iridium complexes
(Elsevier, 2011)Complexes TptolRh(C2H4)2 (1a) and TptolRh(CH2C(Me)C(Me)CH2) (1b) have been prepared by reaction of KTptol with the appropriate ...
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Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: A simple, nonenzymatic access to chiral 2-alkanols
(John Wiley & Sons, 2013)Going chiral! Highly enantioselective catalytic hydrogenations of enol esters 1 by using a Rh catalyst bearing a POP ...
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Large-scale preparation and labelling reactions of deuterated silanes
(John Wiley & Sons, 2012)A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation ...
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Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis
(American Chemical Society, 2023)The incorporation of boron functionalities into transition-metal catalysts has become a promising strategy to improve ...
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Mechanistic Investigations on Hydrogenation, Isomerization and Hydrosilylation Reactions Mediated by a Germyl-Rhodium System
(Wiley, 2022)We recently disclosed a dehydrogenative double C−H bond activation reaction in the unusual pincer-type rhodium-germyl ...