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Tesis Doctoral
Artículo
Coupling of Aromatic Aldehydes with CO2Me-Substituted TpMe2Ir(III) Metallacyclopentadienes
(American Chemical Society, 2012)
The fully CO2Me substituted aquo-iridacyclopentadiene 1 reacts with a variety of aromatic aldehydes, at 90–120 °C, with the formation of bicyclic Fischer-type carbenes, generated by the transfer of the aldehydic H atom to ...
Artículo
Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
(American Chemical Society, 2017)
Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient E-selective alkyne hydrosilylation ...
Artículo
Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols
(Royal Society of Chemistry, 2019)
The synthesis and double asymmetric hydrogenation of (Z,Z)-1,3- diene-1,4-diyl diacetates is described. In this reaction C2/meso ratios up to 85 : 15 and enantioselectivities up to 97% ee have been achieved. As the ...
Artículo
Structural Snapshots of π-Arene Bonding in a Gold Germylene Cation
(Wiley, 2020)
Heavier group 14 element cations exhibit a remarkable reactivity that has typically hampered their isolation. For the few available examples, the role of π-arene interactions is crucial to provide kinetic stabilization, ...
Artículo
Structural diversity and magnetic properties of copper(ii) quinaldinate compounds with amino alcohols
(Royal Society of Chemistry, 2022)
The reactions between [Cu(quin)2(H2O)] (quin− = the anionic form of quinoline-2-carboxylic acid) and a series of aliphatic amino alcohols have yielded structurally very diverse copper(II) complexes, labelled a–g. Single-crystal ...
Artículo
Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)
(Royal Society of Chemistry, 2022-03-18)
Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic activation of the C≡C bond and its insertion into the platinacyclic fragment of 1a that contains the ...
Artículo
Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
(Wiley, 2020)
Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent privileged architectures to acquire fundamental understanding of bimetallic bonding. This has important ...
Artículo
Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites
(Royal Society of Chemistry (Great Britain), 2012)
New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) have been prepared and structurally characterized. The steric hindrance exerted by the Ar Xyl2 groups ...
Artículo
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
(Wiley-Blackwell, 2020)
A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) metal-only frustrated Lewis pair (FLP) is described herein. The drastic effects on H2 activation derived ...