Browsing by Author "Ríos Moreno, Pablo"
Now showing items 1-16 of 16
-
Article
Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different
(Royal Society of Chemistry, 2022)In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
-
Article
Ambiphilic boryl groups in a neutral Ni(ii) complex: a new activation mode of H2
(Royal Society of Chemistry, 2021)The concept of metal–ligand cooperation opens new avenues for the design of catalytic systems that may offer alternative ...
-
Article
Bonding Situation of σ-E−H Complexes in Transition Metal and Main Group Compounds
(Wiley-Blackwell, 2022)The ambiguous bonding situation of σ-E−H (E=Si, B) complexes in transition metal compounds has been rationalized by means ...
-
Article
Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
(John Wiley & Sons, 2016)The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ...
-
Article
Cleavage of Carbon Dioxide C=O Bond Promoted by Nickel-Boron Cooperativity in a PBP-Ni Complex
(Wiley-Blackwell, 2023)The synthesis and characterization of (tBuPBP)Ni(OAc) (5) by insertion of carbon dioxide into the Ni−C bond of (tBuPBP)NiMe ...
-
PhD Thesis
Compuestos organometálicos en reacciones de acoplamiento deshidrogenante, transformación de dióxido de carbono y otros procesos catalíticos.
(2019-02-22)El objetivo de esta Tesis Doctoral consiste en el empleo de ligandos con diferentes propiedades estereoelectrónicas y su ...
-
Article
Enhancing the catalytic properties of well-defined electrophilic platinum complexes
(Royal Society of Chemistry, 2020)Platinum complexes have been often considered as the least reactive of the group 10 triad metals. Slow kinetics are behind ...
-
Article
Hydrosilylation of Carbonyl Compounds Catalyzed by a Nickel Complex Bearing a PBP Ligand
(Wiley, 2021)The efficient catalytic hydrosilylation of ketones and aldehydes has been investigated using a nickel pincer hydride complex ...
-
Article
Ligand Effects in Carbon−Boron Coupling Processes Mediated by σ-BH Platinum Complexes
(Wiley, 2021)The reaction of tri-coordinated boranes (derived from dioxaborolanes and diazaborolanes) with cyclometalated low-electron ...
-
Article
Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex
(American Chemical Society, 2016)This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
-
Article
Reversible carbon-boron bond formation at platinum centers through σ-BH complexes
(Royal Society of Chemistry, 2021)A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, ...
-
Article
Selective catalytic synthesis of amino-silanes at part-per million catalyst loadings
(Royal Society of Chemistry, 2018)Platinum(II) complex [Pt(It Bu0 )(It Bu)][BArF 4] (1a) is a highly active and selective catalyst in the dehydrocoupling ...
-
Article
Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex
(American Chemical Society, 2016)Selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have ...
-
Article
Tetracopper σ-Bound μ-Acetylide and -Diyne Units Stabilized by a Naphthyridine-based Dinucleating Ligand
(Wiley-Blackwell, 2023)Reactions of a dicopper(I) tert-butoxide complex with alkynes possessing boryl or silyl capping groups resulted in formation ...
-
Article
σ-Silane Platinum(II) Complexes as Intermediates in C−Si Bond-Coupling Processes
(Wiley, 2019)Platinum complexes [Pt(NHC’)(NHC)][BArF] (NHC’ denotes the cyclometallated N-heterocyclic carbene ligand, NHC) react ...
-
Article
σ‑GeH and Germyl Cationic Pt(II) Complexes
(ACS, 2022)The low electron count Pt(II) complexes [Pt(NHC′)(NHC)]- [BArF] (where NHC is a N-heterocyclic carbene ligand and NHC′ ...