Browsing by Author "Pérez Jiménez, Marina"
Now showing items 1-8 of 8
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Article
Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo2LiH2, Mo2Li2H4, and Mo6Li9H18 Clusters
(American Chemical Society, 2021)The reactions of LiAlH4 as the source of LiH with complexes that contain (H)Mo≣Mo and (H)Mo≣Mo(H) cores stabilized by the ...
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Article
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
(Wiley-Blackwell, 2020)A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) ...
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Article
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
(Royal Society of Chemistry, 2018)Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ...
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PhD Thesis
Reactivity of Quadruply Bonded Dimolybdenum Hydride Centres: Elementary Organometallic Reactions and Coordination to Main-Group Metal‒Carbon and Metal‒Hydrogen Bonds
(2021-07-08)En esta Tesis se investigan complejos bimetálicos de molibdeno estabilizados por ligandos amidinato bidentados voluminosos ...
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Article
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
(Royal Society of Chemistry, 2022-09-06)There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for ...
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Article
Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds
(German Chemical Society, 2022)LiCH3 and LiCH2CH3 react with the complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1⋅thf) with coordination of two molecules of LiCH2R ...
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Article
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
(American Chemical Society, 2020)Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. ...
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Article
Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
(Royal Society of Chemistry, 2022)More than four decades ago, a complex identified as the planar homoleptic lithium nickelate “Li3NiPh3(solv)3” was reported ...